Results 111 to 120 of about 2,703,176 (382)
Cavity Catalysis by Cooperative Vibrational Strong Coupling of Reactant and Solvent Molecules
Angewandte Chemie, 2018 Here, we report the catalytic effect of vibrational strong coupling (VSC) on the solvolysis of para‐nitrophenyl acetate (PNPA), which increases the reaction rate by an order of magnitude. This is observed when the microfluidic Fabry–Perot cavity in which
Jyoti Lather +4 more
semanticscholar +1 more source
Autophagy in cancer and protein conformational disorders
FEBS Letters, EarlyView.Autophagy plays a crucial role in numerous biological processes, including protein and organelle quality control, development, immunity, and metabolism. Hence, dysregulation or mutations in autophagy‐related genes have been implicated in a wide range of human diseases.
Sergio Attanasio
wiley +1 more source
FEBS Letters, EarlyView.The protonated form of butyrate, as well as other short‐chain fatty acids (SCFAs), is membrane permeable. In acidic extracellular environments, this can lead to intracellular accumulation of SCFAs and cytosolic acidification. This phenomenon will be particularly relevant in acidic environments such as the large intestine or tumor microenvironments ...
Muwei Jiang +2 more
wiley +1 more source
Porosity and morphology control of mesoporous Cu-BTC Metal-Organic Framework microparticles [PDF]
Progress in Physics of Applied MaterialsIn this study, Cu-BTC structures, one of the most widely used metal-organic frameworks (MOF), were synthesized by solvothermal technique, and the effect of metal-to-ligand ratio and the solvent content on their crystalline structure, chemical bonding ...
Kobra Vazirinezhad +2 more
doaj +1 more source
Influence of Solvent Coordination on Hybrid Organic–Inorganic Perovskite Formation
, 2018 Solution-processed hybrid organic–inorganic perovskites (HOIPs) from organoammonium halide and lead halide precursors form efficacious active layers for photovoltaics, light-emitting diodes, and flexible electronics.
J. Hamill, J. Schwartz, Y. Loo
semanticscholar +1 more source
A stepwise emergence of evolution in the RNA world
FEBS Letters, EarlyView.How did biological evolution emerge from chemical reactions? This perspective proposes a gradual scenario of self‐organization among RNA molecules, where catalytic feedback on random mixtures plays the central role. Short oligomers cross‐ligate, and self‐assembly enables heritable variations. An event of template‐externalization marks the transition to
Philippe Nghe
wiley +1 more source
Generalized Born Implicit Solvent Models for Biomolecules.
Annual Review of Biophysics, 2019 It would often be useful in computer simulations to use an implicit description of solvation effects, instead of explicitly representing the individual solvent molecules. Continuum dielectric models often work well in describing the thermodynamic aspects
A. Onufriev, D. Case
semanticscholar +1 more source
FEBS Letters, EarlyView.The enzyme 5‐lipoxygenase (5‐LOX) catalyzes the first step in the biosynthesis of leukotrienes (LTs) involved in inflammatory pathophysiology. After cellular stimulation, 5‐LOX translocates to the nucleus, interacting with the 5‐LOX‐activating protein (FLAP) to form LTA4 from arachidonic acid (AA).
Erik Romp +5 more
wiley +1 more source
A thermodynamic approach to choosing pervaporatives membranes
Ingeniería e Investigación, 2006 This work describes separating a mixture of several components obtained as a product of methyl polymethyl metha- crylate (PMMA) thermo-degradation. It was aimed at purifying methyl methacrylate monomer (MMA) obtained by 95% mass thermal degradation to ...
Mahacine Amrani
doaj
Gaussian field theory for the Brownian motion of a solvated particle
, 2013 An alternative derivation of Brownian motion is presented. Instead of supplementing the linearized Navier-Stokes equation with a fluctuating force, we directly assume a Gaussian action functional for solvent velocity fluctuations.
Speck, Thomas
core +1 more source