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Solvents and Solvent Effects in Organic Chemistry
2002INTRODUCTION SOLUTE-SOLVENT INTERACTIONS Solutions Intermolecular Forces Solvation Preferential Solvation Micellar Solvation (Solubilization) Ionization and Dissociation CLASSIFICATION OF SOLVENTS Classification of Solvents According to Chemical Constitution Classification of Solvents Using Physical Constants Classification of Solvents in Terms of Acid-
C. Reichardt
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High Concentration of Ti3C2Tx MXene in Organic Solvent.
ACS Nano, 2021MXenes are currently one of the most widely studied two-dimensional materials due to their properties. However, obtaining highly dispersed MXene materials in organic solvent remains a significant challenge for current research.
Qingxiao Zhang+5 more
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Solvent Engineering of the Precursor Solution toward Large‐Area Production of Perovskite Solar Cells
Advances in Materials, 2021Solar cells based on emerging organic–inorganic hybrid perovskite materials have reached certified power conversion efficiency as high as 25.5%, showing great potential in the next generation of photovoltaics toward large‐scale industrialization.
Lingfeng Chao+6 more
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Solvent effect in a “solvent free” reaction
CrystEngComm, 2007Vapour digestion of a mixture of solid [Fe(η5-C5H4–C5H4N)2] and solid pimelic acid HOOC(CH2)5COOH in the presence of solvent vapours generates co-crystals of different stoichiometry depending on the protic or aprotic nature of the solvent. The nature of the products has been ascertained by a combined use of SSNMR and X-ray diffraction.
BRAGA D+6 more
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Study of solute–solvent and solvent–solvent interactions in pure and mixed binary solvents
Journal of Molecular Liquids, 2008Abstract Solute–solvent and solvent–solvent interactions have been studied in fifteen pure solvents and seven binary aqueous mixtures by monitoring the solubility of a dye in the solvents. The standard Gibbs energy of solvation, as given by log s , where s is the solubility has been found to depend on various modes of solute–solvent interaction ...
Sanjib Bagchi, Angshuman Maitra
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Novel solvent properties of choline chloride/urea mixtures.
Chemical Communications, 2003Eutectic mixtures of urea and a range of quaternary ammonium salts are liquid at ambient temperatures and have interesting solvent properties.
A. Abbott+4 more
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, 1998
A new implementation of the conductor-like screening solvation model (COSMO) in the GAUSSIAN94 package is presented. It allows Hartree−Fock (HF), density functional (DF) and post-HF energy, and HF and DF gradient calculations: the cavities are modeled ...
V. Barone, M. Cossi
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A new implementation of the conductor-like screening solvation model (COSMO) in the GAUSSIAN94 package is presented. It allows Hartree−Fock (HF), density functional (DF) and post-HF energy, and HF and DF gradient calculations: the cavities are modeled ...
V. Barone, M. Cossi
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Solvents and Solvent Effects: An Introduction [PDF]
Solution chemistry is carried out in solvents, that is in liquids under the conditions of application, which can exert a considerable influence on the properties of the dissolved solute species. A short historical overview on the influence of solvents on chemical processes (equilibria, reaction rates) and physical processes (absorption spectra ...
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Solvatochromic Dyes as Solvent Polarity Indicators
, 1994This review compiles positively and negatively solvatochromic compounds which have been used to establish empirical scales of solvent polarity by means of UV/vis/near-IR spectroscopic measurements in solution-with particular emphasis on the E ~ ( 3 0 ...
C. Reichardt
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Green Chemistry, 2019
A recyclable and green biomass-derived deep eutectic solvent (DES) pretreatment was developed to deconstruct the recalcitrant structure of Eucalyptus for further cellulose enzymatic saccharification and lignin valorization.
Xiaojun Shen+6 more
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A recyclable and green biomass-derived deep eutectic solvent (DES) pretreatment was developed to deconstruct the recalcitrant structure of Eucalyptus for further cellulose enzymatic saccharification and lignin valorization.
Xiaojun Shen+6 more
semanticscholar +1 more source