Effect of excess free energy of solvents on the oxidation of methionine by quinolinium fluorochromate: A kinetic study [PDF]
The oxidation of methionine by quinolinium fluorochromate (QFC) was studied in the presence of chloroacetic acid, in water/organic solvent mixtures of varying excess molar free energy function.
Bhuvaneshwari D.S., Elango K.P.
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Solvent Effects on Electrophilicity
Continuum solvent effect on the electrophilicity index recently proposed by Parr and co-workers (Parr, R. G.; von Szentpaly, L.; Liu, S. J. Am. Chem. Soc. 1999, 121, 1922) is discussed in detail. Solvent effect is introduced using the self-consistent isodensity polarized continuum model (SCI-PCM).
Pérez, Patricia +2 more
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Solute Effects on the Helix-Coil Transition [PDF]
We discuss the effects of the solvent composition on the helix-coil transition of a polypeptide chain. We use a simple model to demonstrate that improving the hydrogen-bonding ability of the solvent can make the transition less cooperative, without ...
Farago, Oded, Pincus, Philip
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In situ growth of NixSy on nickel foam (NixSy/NF) has been investigated by hydrothermal or solvothermal process in water, ethanol and their mixture. XRD shows that the obtained NixSy is consisted of Ni3S2 and NiS in the three solvents.
Yong-Ming Chai +7 more
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Novel Approach to the Preparation of Lead Chalcogenide Colloidal Quantum Dots and Properties Thereof
In this work, we report the study of resizing of lead chalcogenide quantum dots, both PbS and PbSe, in the presence of the oleylamine/oleic acid mixture. We demonstrate that the resizing of lead chalcogenide nanocrystals could be performed in aprotic non-
Ivan A. Shuklov, Irina I. Soboleva
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Structure variation and evolution in microphase-separated grafted diblock copolymer films [PDF]
The phase behavior of grafted d-polystyrene-block-poly(methyl methacrylate) diblock copolymer films is examined, with particular focus on the effect of solvent and annealing time.
Griffiths, Guy H. +3 more
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Trisübstitüe Hetarilazo İndol Boyalarının Sentezi ve Absorpsiyon Özelliklerinin İncelenmesi
Bu çalışmada, çeşitli aromatik aminler ile hazırlanan diazonyum tuzlarının, 2-(4-metilfenil)-1H-indol ve 2-(4-klorfenil)-1H-indol bileşikleri ile azo kenetlenmesi sonucu, bir dizi yeni hetarilazo indol boyası sentezlendi.
Mehmet ULUTÜRK, Tahir TİLKİ
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Modelos contínuos do solvente: fundamentos Continuum solvation models: fundamentals
Continuum solvation models are nowadays widely used in the modeling of solvent effects and the range of applications goes from the calculation of partition coefficients to chemical reactions in solution.
Josefredo R. Pliego Jr
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Solvent-dependent synthesis and mono-hydrolysis of di-Schiff base of (+/-)trans-1,2-cyclohexanediamine and 2-pyridinecarboxaldehyde in Cu(II), Co(II) and Zn(II) complexes [PDF]
The Schiff base ligand trans-N,N′-bis[2-pyridinecarboxylidene] cyclohexane-1,2-diamine (L) was synthesized. This ligand when stirred with 1 equiv of MCl2.xH2O (M = Cu, Co, Zn) in ethanol, undergoes partial hydrolysis of the imino bond and the result ...
Lashanizadegan Maryam, Sarkheil Marzieh
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Solvent Effects in Molecular Recognition. [PDF]
Abstract
D. B. Smithrud +7 more
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