Amphiphilic Block Copolymer Micelles in Selective Solvents: The Effect of Solvent Selectivity on Micelle Formation. [PDF]
We investigated the micellar behavior of a series of asymmetric polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) block copolymers in different P4VP-selective alcoholic solvents. The micellar behavior was further correlated with the spectroscopic ellipsometry results obtained on swelling of PS and P4VP polymer films in the corresponding solvent ...
Kumar L +5 more
europepmc +4 more sources
Precise control of selectivity in nitrobenzene hydrogenation is a long-standing challenge, especially under solvent-free conditions. The PdOx is the key species for enhancing H2 dissociation and nitrobenzene conversion.
Jiaben Wang +11 more
doaj +3 more sources
Matrix-Driven Modulation of Phenolic Profiles from Euterpe oleracea and Oenocarpus bacaba Using Natural Deep Eutectic Solvents [PDF]
This study investigated the influence of solvent composition on the extraction efficiency and selectivity of phenolic compounds from the Amazonian fruits açaí (Euterpe oleracea) and bacaba (Oenocarpus bacaba).
Saulo Victor e Silva +8 more
doaj +2 more sources
Comparison of selectivity of ethylene glycol synthesis and glyceraldehyde biomolecule through Formose reaction in water and methanol solvent [PDF]
In the present paper, the Formose reaction to produce polyols in methanol solvent in the presence of an aerosil (fumed silica) catalyst is first investigated.
Arash Vojood +4 more
doaj +1 more source
System maps for the individual system constant of the solvation parameter model and five binary solvent containing 20–70% (v/v) acetonitrile, acetone, methanol, 2-propanol, and tetrahydrofuran on a single octadecylsiloxane-bonded silica column (Luna C18)
Colin F. Poole, Sanka N. Atapattu
doaj +1 more source
Liquid-Liquid Extraction in a Microextractor: A Laboratory Examination and Thermodynamic Modeling of N-Hexane + Benzene + Sulfolane System [PDF]
This study aimed at investigating liquid-liquid extraction of the three-component n-hexane + benzene + sulfolane system in a micro extractor. Experiments were carried out in a microtube with a diameter of 800μm using a T-shaped micromixer at a residence ...
Majid Mohadesi +2 more
doaj +1 more source
In solution, the solvent determines the molecular conformation and the chemical reaction viability and selectivity. When solvent-solute and solvent-solvent interactions present similar strengths, explicit salvation is the best way to describe a system ...
Joseelyne Hernández-Lima +5 more
doaj +1 more source
A selective Oxidation of Sulfides with Hydrogen peroxide in the Presence of New o-Aminophenol Molybdenum Complex : Sulfoxide vs. sufones [PDF]
An efficient and eco-compatible route for the selective oxidation of a variety of sulfides to the corresponding sulfones with 30% aqueous H2O2 as an oxidant and a molybdenum complex as a catalyst, is described. This new o-aminophenol based oxo-molybdenum
Elham Safaei, Zahra Alaji
doaj +1 more source
In the aerobic oxidation of aldehydes to acids, how the solvent affect the reaction remains unclear. Herein, the solvent effect in the oxidation of 2-ethylhexanal (2-ETH) to 2-ethylhexanoic acid (2-ETA) was systematically investigated.
Zheng Wang +7 more
doaj +1 more source
Solvent-Induced Selectivity of Isoprene From Bio-Derived Prenol
In this work we demonstrate the selective catalytic conversion of prenol, which is an allylic alcohol that can be prepared from renewable resources to isoprene.
Jotheeswari Kothandaraman +2 more
doaj +1 more source

