Results 131 to 140 of about 61,544 (244)

Developing slurries for carbon capture: From synthetic gas mixtures to flue gas

AIChE Journal, EarlyView.
Abstract Deep eutectic solvent (DES)‐based systems have recently emerged as promising alternatives to conventional liquid sorbents for CO2 capture due to their tunable properties and potential for enhanced mass transfer. In this work, two DES‐based slurry systems previously developed for CO2 capture, one aqueous and one non‐aqueous, were further ...
Sahar Foorginezhad, Elena Wikberg, Fredrik Weiland, Xiaoyan Ji   +3 more
wiley   +1 more source

Stabilizing Zinc Anodes via a Zeolite‐Induced Localized Supersaturated Electrolyte Interface

Angewandte Chemie, EarlyView.
A low‐Si/Al‐ratio ZSM‐5 (LZ5) interphase induces a localized supersaturated electrolyte interface on Zn, with a local Zn2+ concentration exceeding 10 M in a 1 M ZnSO4 bulk electrolyte. Continuous Zn2+ enrichment within the zeolite nanochannels creates an H2O‐deficient, anion‐enriched solvation environment, promoting rapid desolvation, uniform ...
Xiaoqi Liu, Yipu Xu, Linjiao Wei, Hongman Sun, Zhengxing Qin, Xizhi Zhang, Dahai Zhang, Xianguo Li, Han Hu, Wei Xing, Yu Zhang, Bin Luo, Zifeng Yan   +12 more
wiley   +2 more sources

Machine learning–driven design of catalytic processes for sulfur dioxide oxidation: Lessons from the trenches

AIChE Journal, EarlyView.
Abstract Despite the growing use of ML in chemical engineering, the catalytic conversion of sulfur dioxide (SO2) to sulfur trioxide (SO3) remains underexplored from a data‐driven modeling perspective. This study evaluates an integrated workflow for literature‐derived SO2 oxidation data, combining data curation, preprocessing assessment, machine ...
Farough Agin, Jules Thibault, Clémence Fauteux‐Lefebvre   +2 more
wiley   +1 more source

Regeneration‐Optimized Chemisorbents: Evaluating Hybrid Coordination Networks for Atmospheric Water Harvesting

Angewandte Chemie, EarlyView.
Atmospheric water harvesting (AWH) under arid conditions requires desiccants that load water below 30% RH and regenerate below 60°C, a performance regime traditionally limited to physisorbents. Here, we show that the inherent hydrolytic instability of M′FSIX‐25‐M coordination networks enable regeneration‐optimized chemisorbents (ROCs) with projected ...
Xiang‐Jing Kong, Asif Raza, Lilia Croitor, Andrey Bezrukov, Xia Li, Angela Shipman, William Morris, Carlos J. Solanilla‐Salinas, Adam Hogan, Brian Space, Volodymyr Bon, Stefan Kaskel, Soumya Mukherjee, Alan C. Eaby, Tao He, Michael J. Zaworotko   +15 more
wiley   +2 more sources

Accelerating Discovery of Organic Molecular Crystals via Materials Informatics and Autonomous Experiments

Advanced Intelligent Discovery, EarlyView.
Materials informatics and autonomous experimentation are transforming the discovery of organic molecular crystals. This review presents an integrated molecule–crystal–function–optimization workflow combining machine learning, crystal structure prediction, and Bayesian optimization with robotic platforms.
Takuya Taniguchi, Kazuki Ishizaki, Ryo Fukasawa   +2 more
wiley   +1 more source

Polypyridyl Coordination Motifs as Precursors for Ordered Carbonaceous Frameworks Toward High‐Density Ru Single‐Atom Catalysts

Angewandte Chemie, EarlyView.
Here, we introduce a molecular design principle that fundamentally expands the bottom‐up synthesis of single‐atom catalysts (SACs). Coordinatively flexible polypyridyl units enable bottom‐up formation of ordered carbonaceous frameworks containing atomically dispersed Ru (∼11 wt%) by simple carbonization.
Koki Chida, Tan‐Hao Shi, Takeharu Yoshii, Yuichiro Hayasaka, Yu Gao, Hao Zhang, Nikolay Kosinov, Shigehisa Akine, Kazuhide Kamiya, Kaining Li, Yoshifumi Kondo, Yasutaka Kuwahara, Tomoki Ogoshi, Hirotomo Nishihara   +13 more
wiley   +2 more sources

Functionalized TiO2 Catalysts: Revolutionary Candidate for Low‐Temperature MgH2 and Prospects for Intelligent Integration

Advanced Intelligent Discovery, EarlyView.
Recent advances in TiO2 modification strategies: structure regulation and composite engineering for improved activity and functionality. TiO2 has emerged as a pivotal catalyst for enhancing MgH2, a high‐capacity solid‐state hydrogen storage material, owing to its structural versatility.
Xiaopeng Chu, Jinghao Wang, Haojie Shi, Chuanxin Peng, Jiacheng Qi, Ge Gao, Guoquan Na, Haibo Yu, Kela Xiao, Gangqiang Wu, Zhendong Yao   +10 more
wiley   +1 more source

Modulating Covalent Organic Framework Nanochannel Microenvironments for Sustainable Hydrogen Peroxide Photosynthesis

Angewandte Chemie, EarlyView.
Alkoxy side chains regulate hydrazone‐linked COF nanochannel microenvironments by tuning pore polarity, reactant adsorption, and charge‐separation behavior. The optimized framework facilitates oxygen activation and hydrogen peroxide photosynthesis in real water and a 1 L natural‐sunlight reactor. LCA further shows that natural sunlight and larger‐scale
Ruixue Sun, Shaoyang Gao, Luqiao Feng, Peixuan Xie, Wenyu Shen, Nikita Rog, Marwan Mohammed, Qi Huang, Giulio Santori, Xianfeng Fan, Bien Tan, Cher Hon Lau   +11 more
wiley   +2 more sources

Helical Single Crystals of Porous Hydrogen‐Bonded Organic Frameworks as a Candidate for Morphologically Functional Organic Materials

Angewandte Chemie, EarlyView.
Helical‐shaped crystals of a hydrogen‐bonded organic framework (HOF) with permanent porosity have been developed. The helical HOF shows expansion and contraction, respectively, upon desorption and adsorption of solvents. Moreover, doping of additive molecules can modulate the photophysical properties and morphology of the helical HOF, showing the ...
Yuzuki Murata, Taito Hashimoto, Ryusei Oketani, Miki Naruoka, Yuuya Nagata, Ryosuke Tamura, Masayuki Morimoto, Mio Yamashita, Daisuke Sakamaki, Norimitsu Tohnai, Hitoshi Asakawa, Ichiro Hisaki   +11 more
wiley   +2 more sources

Mathematical Model of Emergency Indoor Air Purification by Powder Aerosol. [PDF]

Toxics
Kudryashova O, Vorozhtsov A.
europepmc   +1 more source