Results 231 to 240 of about 112,917 (304)

Calix[4]arene Design for Enhanced Carbon Capture via Topological Learning

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Solid direct air capture (S‐DAC) technologies have the potential to remove pre‐existing CO2 from the atmosphere by taking advantage of hydrophobic materials that will retain CO2 through physisorption and separating it from the abundant water molecules. Calix[n]arenes are highly tunable and versatile complexes with inherent hydrophobic cavities,
Jeffrey A. Laub   +1 more
wiley   +1 more source

Efficient cation separation based on humidity control and adsorption. [PDF]

open access: yesNat Commun
Liang J   +16 more
europepmc   +1 more source

On the Role of Linker Fluorination in the Adsorption‐Induced Structural Response of CeIV‐Based Metal‐Organic Frameworks

open access: yesChemistry – A European Journal, EarlyView.
The effect of the degree of fluorination of the organic linker on the adsorption behavior of MIL‐140A(Ce) is systematically investigated with a combination of experimental techniques. Cooperative adsorption is switched off in less fluorinated frameworks, as a result of reduced steric hindrance around the adsorption sites.
Francesca Nerli   +11 more
wiley   +1 more source

Toward Larger Cyclo‐9,10‐Anthryleneparaphenylenes

open access: yesChemistry – A European Journal, EarlyView.
During a macrocyclization with a dihydroanthracene diol as corner unit, larger oligomers than the trimer and tetramer were formed and isolated up to the nonamer. Their three‐dimensional structures were studied by X‐ray diffraction. The most abundant macrocycles were rearomatized to the corresponding CPP derivatives.
Moritz P. Schuldt   +3 more
wiley   +1 more source

Self‐Immolative Gels: Programmable Degradation Using Self‐Immolative Linkers and Polymers

open access: yesChemistry – A European Journal, EarlyView.
Self‐immolative linkers and polymers undergo bond‐cleaving reaction cascades in response to specific stimuli. Their incorporation into gels can be harnessed to release cargo, induce property changes, or trigger degradation in a highly controlled manner. These functions can be employed in applications such as sensing and drug delivery.
Chuanfeng Li, Elizabeth R. Gillies
wiley   +1 more source

Conversion Between 2‐ and 3‐Dimensional Halogen‐Bonded Networks Formed From a Single N‐Oxide/Iodoalkyne Building Block

open access: yesChemistry – A European Journal, EarlyView.
Open halogen‐bonded networks have been prepared from building blocks that incorporate both iodoalkyne halogen bond donors and a pyridine‐N‐oxide halogen bond acceptor. An initially‐formed 3D network containing dioxane in its channels undergoes an unprecedented transition to a 2D material when crystals are exposed to diethyl ether.
Jordan N. Smith   +4 more
wiley   +1 more source

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