The orphan cytochrome P450 CYP107J1 with unknown redox partners was rationally modified into H2O2‐driven form. The QE (E251Q/T252E) mutant produced valuable chemicals by simply mixing the enzyme with substrate and H2O2. ABSTRACT Cytochrome P450 monooxygenases (P450s) not only play many physiological roles in oxidative metabolism but are also promising ...
Hideki Kato +5 more
wiley +1 more source
The Hemoprotein Hhy1 Promotes Heme‐Dependent Catalase Activity of Ctt1
A Schizosaccharomyces pombe strain deficient in heme (hem1Δ) and siderophore (Fc) biosynthesis, as well as high‐affinity iron (Fe) uptake (blue), was used to uncover the hemoprotein Hhy1 that promotes the heme‐dependent activity of the catalase Ctt1. In contrast, hhy1Δ cells exhibit reduced Ctt1 activity and increased sensitivity to oxidative stress ...
Tobias Vahsen +3 more
wiley +1 more source
Zwitterionic Mn(III)‐Tetraphenyl Porphyrins: Water‐Soluble MRI Contrast Agents with High Relaxivity
Mn(III)‐based contrast agents (MBCAs) are promising and potentially safer alternatives to the Gd(III)‐based contrast agents (GBCAs) currently used in MRI. This study reports the synthesis, physicochemical characterization and first in vivo application of novel Mn(III)‐tetraphenylporphyrin chelates, bearing zwitterionic sulfobetaine or N‐oxide groups ...
Darius Ludolfs +10 more
wiley +1 more source
Soret Effect and Chemical Process on MHD Oscillatory Flow in a Physiological Fluid. [PDF]
Kavitha R, Ladu NSD, Ravi S.
europepmc +1 more source
Metastable phase-separated droplet generation and long-time DNA enrichment by laser-induced Soret effect. [PDF]
Kobayashi M, Minagawa Y, Noji H.
europepmc +1 more source
Porphyrin‐Geländer–Helical Conjugated Banister Type Porphyrin Dyads
Porphyrin arrays go chiral–A porphyrin Geländer macrocycle represents the intriguing prototype architecture of helically chiral butadiyne‐linked porphyrin arrays. This study combines synthetic, spectroscopic, and computational methods to shed light on its structure, chiroptical properties, and tunability, highlighting its promise for advancing ...
Joël F. Keller +2 more
wiley +1 more source
Soret-Effect Induced Phase-Change in a Chromium Nitride Semiconductor Film. [PDF]
Shuang Y +9 more
europepmc +1 more source
Soret Effect on MHD Casson Fluid over an Accelerated Plate with the Help of Constant Proportional Caputo Fractional Derivative. [PDF]
Abbas S +6 more
europepmc +1 more source
Influence of electronic effects on one- and two-photon absorption in porphyrin isomers [PDF]
Bergendahl, Lisa Therese +1 more
core +1 more source
Thermal analysis of bioconvection flow of CNTs/water based hybrid nanofluid with gyrotactic microbes using artificial neural network. [PDF]
Ben Hamida MB +3 more
europepmc +1 more source

