Results 111 to 120 of about 377,659 (302)

Synthesis and sorption properties of filled fibrous sorbents with immobilized hetarylformazan groups [PDF]

open access: yes, 2003
New sorbents were prepared by immobilization of structurally different sulfur-containing hetaryl-formazans on nonwoven polyacrylonitrile fiber tilled with AV-17 anion exchanger.
Lipunov, I. N.   +4 more
core  

Hydrogenolysis of xylose to C2-C3 diols over Cu-Cr2O3/Al2O3 catalyst

open access: yesХімія, фізика та технологія поверхні
This study is dedicated to the continuous-flow hydrogenolysis of xylose 10 wt. % solutions in a methanol-water mixture to produce ethylene glycol and propylene glycol over Cu-Cr2O3/Al2O3 catalyst.
І.С. Горбанюк   +2 more
doaj   +1 more source

Polymorph‐Specific Electronic Transduction in WO3 during Molecular Sensing

open access: yesAdvanced Materials, EarlyView.
Metal‐oxide polymorphs with similar surface chemistry can nevertheless exhibit distinct sensing properties. In γ‐ and ε‐WO3, analyte adsorption appears comparable; yet, only ε‐WO3 induces a pronounced lattice electronic perturbation that accommodates charge in sub‐conduction band minimum states.
Matteo D'Andria   +6 more
wiley   +1 more source

High Charge Carrier Mobility in Non‐Conjugated 3D Covalent Organic Frameworks

open access: yesAdvanced Materials, EarlyView.
A non‐conjugated 3D COF constructed via boronate ester linkages from tetraphenylene and pyrene‐based monomers is reported, which exhibits a high charge carrier mobility of 14 ± 1 cm2 V−1 s−1. ABSTRACT π‐Conjugation, π–π stacking, and long‐range order play a central role in determining charge transport efficiency in organic materials.
Joaquín Almarza   +11 more
wiley   +1 more source

A Biochar‐Based Composite Hydrogel Microenvironment for Enhanced Biocatalysis

open access: yesAdvanced Materials, EarlyView.
This work presents the synthesis of a polyacrylamide hydrogel wherein biomass‐derived biochar is co‐encapsulated with the enzyme horseradish peroxidase (HRP). The resulting composite hydrogel possesses balanced electron‐rich and electron‐deficient domains, creating an optimal microenvironment that concentrates both hydrogen peroxide and phenol ...
Shengzhe Wang   +9 more
wiley   +1 more source

Positively Charged Polymer‐Brush MOFs for Large‐Area, Pressure‐Resistant Gas Separation Membranes

open access: yesAdvanced Materials, EarlyView.
A universal POPA strategy enables positively charged polymer‐brush MOFs with self‐adaptive interfacial interlocking to resist aggregation under fast processing. This design ensures seamless dispersion within large‐area selective layers, achieving 1 m‐wide roll‐to‐roll fabrication of pressure‐resistant MMCMs with tunable CO2 separation performance ...
Yi Yang   +11 more
wiley   +1 more source

Analysis of Effectivness of Magnetically Labeled Biosorbent Obtained Through the Mechanical and Magnetohydrodynamic Stirring [PDF]

open access: yes, 2016
The efficiency of Cu2+ ion extraction of magnetically labeled biosorbent based on yeast Sacharomyces cerevisiae obtained by magnetohydrodynamic stirring in combined magnetic and electric fields has been determined.
Chyzh, Y. (Yulia)   +5 more
core  

Direct Synthesis of High‐Valence Protein@UiO‐66 Composites: Linking Crystallization Pathways to Protein Encapsulation

open access: yesAdvanced Materials, EarlyView.
This work reports a direct, biocompatible method to synthesize UiO‐66, enabling one‐step encapsulation of proteins without compromising crystallinity or activity. Using advanced in situ and ex situ techniques, the study reveals that proteins integrate concurrently with MOF growth, forming crystalline protein@UiO‐66 nanoparticles, and provide insight ...
Jesús Cases Díaz   +5 more
wiley   +1 more source

Hierarchically Engineered Multi‐Enzyme Nanoreactors for in vitro Drug Biosynthesis and Pathway Transplantation Into Cells

open access: yesAdvanced Materials, EarlyView.
A hierarchically structured metal–organic framework (eMIL) is shown to host the complete six‐enzyme biosynthesis pathway for the anti‐cancer pigment violacein, reshaping reaction dynamics and multiplying in vitro yields. eMIL nanoreactors deliver this reconstituted bacterial multi‐protein system into mammalian cells, where cell‐derived substrates and ...
Ainur Sharip   +12 more
wiley   +1 more source

Phosphoric Acid and Steam as Activation Agents for Carbonized Porous Polymer Surfaces

open access: yesAdsorption Science & Technology, 2006
Carbon sorbents derived from the copolymer of 4,4′-bis(maleimidodiphenyl)methane and divinylbenzene are described. The influence of phosphoric acid treatment and the type of carrier gas used in the carbonization process were studied.
M. Sobiesiak   +3 more
doaj   +1 more source

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