The sorption of molecules of different size and polarity (water, n-hexane ...
Sorption Capacity
core
A linker‐locking strategy rigidifies the flexible metal–organic framework (MOF) MIL‐53‐(OH)2 via the cooperative encapsulation of ligands and structural water. This network significantly enhances the framework's aqueous stability. Crucially, rigidification suppresses enol emission to yield a single keto tautomer state with an extended lifetime ...
Amitosh Sharma +8 more
wiley +1 more source
Intrinsic Superprotonic Conduction in Metal‐Free Hydrogen‐Bonded Organic–Inorganic Frameworks
A simple hybridization strategy yields a suite of metal‐free hydrogen‐bonded organic‐inorganic frameworks (HOIFs) with dense, uninterrupted hydrogen‐bonded networks that possess intrinsically high superprotonic conductivity, establishing a versatile and scalable platform for high‐performance solid‐state proton conductors.
Jin Chen +14 more
wiley +1 more source
Sorption of Water Vapor on Poly (ethylene terephthalate) Micro Fibers by Inverse Gas Chromatography [PDF]
P(論文)The behaviors of water vapor sorption were measured at 60-90℃ with inverse gas chromatography for poly (ethylene terephthalate) fibers having diameters, 8, 7 and 4μm. The diameters and the crystallinities were measured with SEM and X-ray diffraction
MARUI, MASAKI +23 more
core
Engineering an Artificial Metalloenzyme for Efficient Photo‐Enzymatic CO2 Conversion
We built a light‐driven artificial metalloenzyme by covalently conjugating formate dehydrogenase (FDH) with a tailored rhodium complex (Rh‐L6) to overcome spatial‐separation‐limited electron transfer. This integration boosts NADH regeneration and CO2 conversion, giving 2.31‐fold higher formate yield than physical mixtures, due to a narrowed bandgap and
Mengxue Kang +6 more
wiley +1 more source
Self‐Healing Pd(II) Cage Metallogels for Iodine Capture in Water and Heterogeneous Photocatalysis
Two carbazole‐derived metal‐organic cages hierarchically self‐assemble into supramolecular metallogels that integrate autonomous self‐healing, reversible stimuli responsiveness, high‐capacity aqueous iodine capture, and visible‐light‐driven photocatalytic sulfide oxidation within a single multifunctional platform.
Monotosh Dalapati +3 more
wiley +1 more source
Interfacial Salt Redistribution Enables Rapid Atmospheric Water Harvesting in a Biomimetic Multi‐Layer Hygroscopic Membrane [PDF]
A biomimetic multi‐layer hygroscopic membrane redistributes salt toward an air‐accessible nanofiber interface, enabling rapid interfacial deliquescence while a brush‐like hydrogel promotes efficient liquid transport and storage. By decoupling vapor capture from bulk water storage, the membrane achieves fast sorption kinetics and enables rapid‐cycling ...
Zhong F +8 more
europepmc +2 more sources
Sorption of ionisable organic compounds by field soils. Part 2: cations, bases and zwitterions
Sorption of a range of permanent cations, bases and zwitterionic compounds was measured as a function of pH in two soil types. Pyridinium cations were more strongly sorbed (K(d) 10- > 1000) than aliphatic cations (K(d) 6.
Evans, A. A., Nicholls, P. H.
core +1 more source
Scalable Fabrication of MOF Glass Membranes for Gas Separation via Stepwise Phase Transition
Metal‐organic framework (MOF) glass membranes, with their excellent processability and permanent pore structure, have great potential for gas separation applications. However, during large‐scale fabrication, defects and obvious cracks are prone to occur due to the limitations of powder processing.
Mao Ye +14 more
wiley +1 more source
Quenching Photo‐Induced Free Radicals Endows Superomniphobic Atmospheric Water Harvesting Hydrogels With UV Resistance for Durable Bifacial Photovoltaic Cooling [PDF]
A hygroscopic hydrogel layer functionalized with fullerene C60 tackles heat and dust challenges in bifacial photovoltaics (PV) panels. It resists soiling and photo‐aging, maintains high transparency, absorbs water vapor from the air during the night, and delivers strong evaporative cooling power during daytime, significantly lowering PV panel ...
Zhou X +6 more
europepmc +2 more sources

