Results 141 to 150 of about 175,932 (291)

Accelerating Discovery of Organic Molecular Crystals via Materials Informatics and Autonomous Experiments

Advanced Intelligent Discovery, EarlyView.
Materials informatics and autonomous experimentation are transforming the discovery of organic molecular crystals. This review presents an integrated molecule–crystal–function–optimization workflow combining machine learning, crystal structure prediction, and Bayesian optimization with robotic platforms.
Takuya Taniguchi, Kazuki Ishizaki, Ryo Fukasawa   +2 more
wiley   +1 more source

Tuning Pore Geometry of Zirconium Metal–Organic Frameworks via Bent Ligands for Enhanced Sulfide Oxidation Catalysis

Angewandte Chemie, EarlyView.
Engineering pore geometry through ligand conformational bending enhances active‐site accessibility and mass transport in Zr‐MOFs, leading to superior catalytic sulfide oxidation. ABSTRACT Pore engineering represents a powerful strategy to tailor the physicochemical properties of metal–organic frameworks (MOFs), yet the structure‐activity relationship ...
Zhaoyi Liu, Joshua Rushlow, Jiatong Huo, Wenlu Fan, Kui Tan, Shengqian Ma, Rong‐Ran Liang, Hong‐Cai Zhou   +7 more
wiley   +2 more sources

Sorption capacity of phosphate in mineral soils: I Estimation of sorption capacity by means of sorption isotherms

Agricultural and Food Science, 1990
The sorption capacity of phosphate in seven soil samples (clay content 1—70 %, organic carbon content 0.8—10.7 %, soil pH 4.2—5.3, oxalate-extractable Al 11—222 and Fe 11—202 mmol/kg soil) was studied by means of sorption isotherms. The soils were equilibrated, for two to seven days at +5 and +20°C, with solutions containing phosphate 0—10 mmol/l (0 ...
openaire   +5 more sources

Functionalized TiO2 Catalysts: Revolutionary Candidate for Low‐Temperature MgH2 and Prospects for Intelligent Integration

Advanced Intelligent Discovery, EarlyView.
Recent advances in TiO2 modification strategies: structure regulation and composite engineering for improved activity and functionality. TiO2 has emerged as a pivotal catalyst for enhancing MgH2, a high‐capacity solid‐state hydrogen storage material, owing to its structural versatility.
Xiaopeng Chu, Jinghao Wang, Haojie Shi, Chuanxin Peng, Jiacheng Qi, Ge Gao, Guoquan Na, Haibo Yu, Kela Xiao, Gangqiang Wu, Zhendong Yao   +10 more
wiley   +1 more source

Synthesis of Ladder and Flexible Polysulfonimides Directly From Anionic Monomers: Investigating Structure–Property Convergence in Succinonitrile–Polymer Electrolyte Blends

Angewandte Chemie, EarlyView.
Direct synthesis of sulfonimide‐based polymers of intrinsic microporosity enables comparison with compositionally similar flexible analogs. Incorporation of a common pore‐filling transport medium drives these fundamentally different polymer architectures toward similar bulk conductivity and mechanical properties while revealing distinct microscopic ion‐
Abraham Herzog‐Arbeitman, Pablo Leon, Benedikt S. Schreib, KyuJung Jun, Jurgis Ruza, Vanesa Munoz Perales, Yang Shao‐Horn, Rafael Gomez‐Bombarelli, Jeremiah A. Johnson   +8 more
wiley   +2 more sources

Hydrogen sorption properties of the composed system calcium hydride – magnesium boride

, 2010
The hydrogen sorption properties of the calcium hydride – magnesium boride system as evaluated by manometric and calorimetric analyses are ...
G. D’Alì Staiti, F. Agresti, G. Principi, B. Schiavo, MILANESE, CHIARA   +4 more
core  

A Hybrid Ultramicroporous Material Family With Metal‐Controlled Dynamic Behavior

Angewandte Chemie, EarlyView.
The hybrid ultramicroporous material (HUM) family NbOFFIVE‐3,3'‐bpy‐M exhibits metal‐dependent dynamic behavior upon exposure to water vapor. Whereas the Co and Ni variants undergo reversible lp→np→lp induced‐fit transformation, Cu and Zn exhibit a more typical np→lp mechanism.
Aizhamal Subanbekova, Kyriaki Koupepidou, Andrey A. Bezrukov, Asif Raza, Sousa Javan Nikkhah, Han Fang, Soumya Mukherjee, Ze Chang, Matthias Vandichel, Michael Zaworotko   +9 more
wiley   +2 more sources

Elucidating Liquid‐Phase Guest Transport Across MOF Single Crystals: Interplay of Adsorption, Desorption, and Intracrystalline Diffusion

Angewandte Chemie, EarlyView.
Guest transport across metal–organic framework (MOF) single crystals disentangles transport occurring through the micropores from contributions at grain boundaries. Even guest molecules with identical kinetic diameters show drastically different transport behavior arising from the distinct modes of adsorption. Neither pore clogging nor surface collapse
Hochul Woo, Hans Roman Cortina, Adam J. Matzger   +2 more
wiley   +2 more sources

Mechanisms and Factors Affecting Sorption of Microcystins onto Natural Sediments

, 2011
The sorption of microcystins (MCs) to fifteen lake sediments and four clay minerals was studied as a function of sediment/clay properties, temperature, and pH through well-controlled batch sorption experiments.
Xiao, Bangding, Wang, Zhi, Huang, Jiantuan, bdxiao@ihb.ac.cn, Wu, Xingqiang, Li, Renhui, Xiao, BD, Chinese Acad Sci, Inst Hydrobiol, Wuhan 430072, Peoples R China, Wang, Chunbo   +7 more
core  

Regeneration‐Optimized Chemisorbents: Evaluating Hybrid Coordination Networks for Atmospheric Water Harvesting

Angewandte Chemie, EarlyView.
Atmospheric water harvesting (AWH) under arid conditions requires desiccants that load water below 30% RH and regenerate below 60°C, a performance regime traditionally limited to physisorbents. Here, we show that the inherent hydrolytic instability of M′FSIX‐25‐M coordination networks enable regeneration‐optimized chemisorbents (ROCs) with projected ...
Xiang‐Jing Kong, Asif Raza, Lilia Croitor, Andrey Bezrukov, Xia Li, Angela Shipman, William Morris, Carlos J. Solanilla‐Salinas, Adam Hogan, Brian Space, Volodymyr Bon, Stefan Kaskel, Soumya Mukherjee, Alan C. Eaby, Tao He, Michael J. Zaworotko   +15 more
wiley   +1 more source