Results 41 to 50 of about 427,895 (336)

Photocatalytic activity of spectro-pure titanium dioxide: Effects of crystalline structure, specific surface area and sorption properties

open access: yesInternational Journal of Photoenergy, 2003
Dispersed optically pure anatase, rutile and two-phase samples of titanium dioxide were prepared using a sol-gel technique. In particle of two-phase samples, the anatase nuclei are surrounded by a rutile envelope.
Evgeny I. Kapinus   +4 more
doaj   +1 more source

Selective alkylation of toluene over basic zeolites: an in situ infrared spectroscopic investigation [PDF]

open access: yes, 1997
In situinfrared spectroscopy was used to study the sorption and reaction of toluene and methanol over various alkali exchanged X zeolites. The size of the metal cations controls the preference of sorbing methanol or toluene.
Eder-Mirth, G.C.   +3 more
core   +2 more sources

NanoMOF‐Based Multilevel Anti‐Counterfeiting by a Combination of Visible and Invisible Photoluminescence and Conductivity

open access: yesAdvanced Functional Materials, EarlyView.
This study presents novel anti‐counterfeiting tags with multilevel security features that utilize additional disguise features. They combine luminescent nanosized Ln‐MOFs with conductive polymers to multifunctional mixed‐matrix membranes and powder composites. The materials exhibit visible/NIR emission and matrix‐based conductivity even as black bodies.
Moritz Maxeiner   +9 more
wiley   +1 more source

Adsorption-Based Hydrogen Storage in Activated Carbons and Model Carbon Structures

open access: yesReactions, 2021
The experimental data on hydrogen adsorption on five nanoporous activated carbons (ACs) of various origins measured over the temperature range of 303–363 K and pressures up to 20 MPa were compared with the predictions of hydrogen density in the slit-like
Anatoly Fomkin   +7 more
doaj   +1 more source

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

open access: yesAdvanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies   +8 more
wiley   +1 more source

Chemical-physical features of the biochar-based oil-destructive sorbent

open access: yesХімія, фізика та технологія поверхні, 2023
The main task and relevance of this work are to develop the most effective sorbents for cleaning oil pollution or accidental oil spills. A generalized criterion for evaluating the effectiveness of a sorbent is the local availability and fast ...
A. V. Khokhlov
doaj   +1 more source

Zeolite-filled silicone rubber membranes. Experimental determination of concentration profiles [PDF]

open access: yes, 1994
Permeant concentrations in silicalite-filled silicone rubber membranes during pervaporation of propanol/water mixtures were measured using multi-layered membranes.
Bargeman, D.   +6 more
core   +2 more sources

Rational Fine‐Tuning of MOF Pore Metrics: Enhanced SO2 Capture and Sensing with Optimal Multi‐Site Interactions

open access: yesAdvanced Functional Materials, EarlyView.
A pore tuning strategy to amplify the multi‐site MOF‐SO2 interactions is proposed to achieve an enhanced trace SO2 capture and chemiresistive sensing in highly stable isostructural DMOFs by annelating benzene rings. This work provides a facile strategy to achieve tailor‐made stable MOF materials for specific multifunctional applications.
Shanghua Xing   +9 more
wiley   +1 more source

On the Development of Thermochemical Hydrogen Storage: An Experimental Study of the Kinetics of the Redox Reactions under Different Operating Conditions

open access: yesApplied Sciences, 2021
This work aims at investigating the reduction/oxidation (redox) reaction kinetics on iron oxide pellets under different operating conditions of thermochemical hydrogen storage. In order to reduce the iron oxide pellets (90% Fe2O3, 10% stabilizing cement),
Bernd Gamisch   +2 more
doaj   +1 more source

Selective Benzene Capture by Metal‐Organic Frameworks

open access: yesAdvanced Functional Materials, EarlyView.
Metal‐organic frameworks (MOFs) hold significant potential for capturing benzene from air emissions and hydrocarbon mixtures in liquid phases. This capability stems from their precisely engineered structures, versatile chemistries, and diverse binding interactions.
Zongsu Han   +4 more
wiley   +1 more source

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