Results 41 to 50 of about 377,659 (302)

Ideal Molecular Sieving with a Dense MOF for Helium Upgrading with Highly Diffusion Selective Mixed Matrix Membranes

Advanced Functional Materials, EarlyView.
The separation of Helium gas from natural gas is challenging but highly important. MIL‐116(Ga), a “non‐porous” metal–organic framework is used as a molecular sieve to separate He from CH4. Druse‐like MIL‐116(Ga) particles are integrated into polysulfone mixed matrix membranes.
Ayisha Komal, Laura Calderón‐Rodríguez, Oksana Smirnova, Eren Grossmann, Aparna Binu Varghese, Karen Marlenne Garcia Alvarez, Andreas Schneemann, Thomas Hoyer, Ralf Wyrwa, Felix Helmut Schacher, Alexander Knebel   +10 more
wiley   +1 more source

Oxidation of xylose – methanol mixture into methyl lactate and methyl glycolate on CeO2-SnO/AlO3 catalyst

Хімія, фізика та технологія поверхні
The development of catalytic methods for xylose transformation as renewable raw material into value-added chemicals such as lactic and glycolic acid esters has been the subject of intensive research in recent years.
S. V. Prudius, N. L. Hes, A. Yu. Zhuravlov, V. V. Brei   +3 more
doaj   +1 more source

Photocatalytic activity of spectro-pure titanium dioxide: Effects of crystalline structure, specific surface area and sorption properties

International Journal of Photoenergy, 2003
Dispersed optically pure anatase, rutile and two-phase samples of titanium dioxide were prepared using a sol-gel technique. In particle of two-phase samples, the anatase nuclei are surrounded by a rutile envelope.
Evgeny I. Kapinus, Tatyana A. Khalyavka, Valentina V. Shimanovskaya, Tatyana I. Viktorova, Vladimir V. Strelko   +4 more
doaj   +1 more source

Advancing Electronic Application of Coordination Solids: Enhancing Electron Transport and Device Integration via Surface‐Mounted MOFs (SURMOFs)

Advanced Functional Materials, EarlyView.
The layer‐by‐layer (LbL) assembly of coordination solids, enabled by the surface‐mounted metal‐organic framework (SURMOF) platform, is on the cusp of generating the organic counterpart of the epitaxy of inorganics. The programmable and sequential SURMOF protocol, optimized by machine learning (ML), is suited for accessing high‐quality thin films of ...
Zhengtao Xu, Christof Wöll, Stefan Bräse   +2 more
wiley   +1 more source

NanoMOF‐Based Multilevel Anti‐Counterfeiting by a Combination of Visible and Invisible Photoluminescence and Conductivity

Advanced Functional Materials, EarlyView.
This study presents novel anti‐counterfeiting tags with multilevel security features that utilize additional disguise features. They combine luminescent nanosized Ln‐MOFs with conductive polymers to multifunctional mixed‐matrix membranes and powder composites. The materials exhibit visible/NIR emission and matrix‐based conductivity even as black bodies.
Moritz Maxeiner, Ruben Maile, Murat Cuvalli, Andreas Wolf, Ayisha Komal, Robert Oestreich, Christoph Janiak, Karl Mandel, Alexander Knebel, Klaus Müller‐Buschbaum   +9 more
wiley   +1 more source

Selective alkylation of toluene over basic zeolites: an in situ infrared spectroscopic investigation [PDF]

, 1997
In situinfrared spectroscopy was used to study the sorption and reaction of toluene and methanol over various alkali exchanged X zeolites. The size of the metal cations controls the preference of sorbing methanol or toluene.
Eder-Mirth, G.C., Lercher, J.A., Palomares gimeno, A.E., Palomares, A.E.   +3 more
core   +2 more sources

Chemical-physical features of the biochar-based oil-destructive sorbent

Хімія, фізика та технологія поверхні, 2023
The main task and relevance of this work are to develop the most effective sorbents for cleaning oil pollution or accidental oil spills. A generalized criterion for evaluating the effectiveness of a sorbent is the local availability and fast ...
A. V. Khokhlov
doaj   +1 more source

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

Advanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies, Marcos Eduardo G. Carmo, Gonçalves J. Marrenjo, Stephan Reuther, Patrick Ganswindt, Antonio Otavio T. Patrocinio, Thomas Bein, Osmando F. Lopes, Jenny Schneider   +8 more
wiley   +1 more source

On the Development of Thermochemical Hydrogen Storage: An Experimental Study of the Kinetics of the Redox Reactions under Different Operating Conditions

Applied Sciences, 2021
This work aims at investigating the reduction/oxidation (redox) reaction kinetics on iron oxide pellets under different operating conditions of thermochemical hydrogen storage. In order to reduce the iron oxide pellets (90% Fe2O3, 10% stabilizing cement),
Bernd Gamisch, Matthias Gaderer, Belal Dawoud   +2 more
doaj   +1 more source

Rational Fine‐Tuning of MOF Pore Metrics: Enhanced SO2 Capture and Sensing with Optimal Multi‐Site Interactions

Advanced Functional Materials, EarlyView.
A pore tuning strategy to amplify the multi‐site MOF‐SO2 interactions is proposed to achieve an enhanced trace SO2 capture and chemiresistive sensing in highly stable isostructural DMOFs by annelating benzene rings. This work provides a facile strategy to achieve tailor‐made stable MOF materials for specific multifunctional applications.
Shanghua Xing, Abdulrahman Mohabbat, István Boldog, Jens Möllmer, Marcus Lange, Yulyan Haiduk, Tobias Heinen, Vladimir Pankov, Oliver Weingart, Christoph Janiak   +9 more
wiley   +1 more source