Results 101 to 110 of about 74,577 (229)

More Than a Buffer in Biochemistry: Tris as an Architect and Gatekeeper of Metal–Oxo Assembly

open access: yesAngewandte Chemie International Edition, EarlyView.
Tris(hydroxymethyl)aminomethane, depicted as an octopus, acts as an alkoxy ligand, chelator, and structure‐directing buffer that programs polyoxometalate's speciation, nucleation, and heterometal insertion in aqueous solution. ABSTRACT Polyoxometalates (POMs, molecular metal–oxo clusters) are typically studied and applied in aqueous media, where ...
Nadiia I. Gumerova, Annette Rompel
wiley   +1 more source

Radium Speciation in Simulated Digestive Biofluids: Insights from Electrospray Ionization Mass Spectrometry and Thermodynamic Modeling

open access: yesAnalysis &Sensing, EarlyView.
Electrospray ionization mass spectrometry (ESI‐MS) combined with thermodynamic modeling provides the first direct characterization of radium speciation in synthetic gastrointestinal biofluids. Free Ra2+ ions predominate with minimal protein binding and negligible EDTA complexation. Crown ethers enable effective Ra complexation.
Linus Holtmann   +5 more
wiley   +1 more source

Research on the Detoxification of Municipal Solid Waste Incineration Fly Ash: Organic Acid Washing Pretreatment Coupled With Cement/DDTC Stabilization

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Heavy metals in municipal waste incineration fly ash are potentially harmful to the ecological environment and human health. To mitigate the hazards of fly ash, this study attempts to detoxify fly ash through organic acid washing pretreatment coupled with cement/sodium diethyldithiocarbamate (DDTC) solidification.
Junfeng Pang   +4 more
wiley   +1 more source

Fe(II)/Chlorine‐Driven Advanced Oxidation of Textile Dyes in a Tubular Microreactor: Continuous‐Flow Performance and Matrix Effects

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT The Fe(II)/chlorine system has emerged as a promising advanced oxidation technology for water treatment, yet its application in continuous‐flow systems remains unexplored. This study presents the first comprehensive investigation of the Fe(II)/chlorine process in a tubular microreactor, a setup that significantly enhances mass transfer and ...
Abderrahmane Talbi   +2 more
wiley   +1 more source

Integrated Evaluation of Contaminant Profiles, Detection Techniques, and Management Strategies for Tannery Sludge

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT This review article critically examines the environmental and health hazards of tannery sludge (TS), a complex by‐product of the leather tanning industry. TS is characterized by a diverse array of contaminants, including heavy metals like chromium, organic pollutants such as polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds ...
Yashar Aryanfar   +10 more
wiley   +1 more source

Sustainable Graphene Oxide–Intercalated Bentonite Composite for the Effective Removal of Imidacloprid From Water: Adsorption Performance, Isotherm, and Kinetics

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Water is a fundamental necessity for our existence, but its rapid contamination is causing devastating effects on the environment and health of living species worldwide. Adsorptive removal of pollutants is one of the popular water treatment techniques because of its simplicity, affordability, and the broad range of available adsorbents.
Priyanka Negi   +3 more
wiley   +1 more source

Native Cryo-Correlative Light and Synchrotron X‑ray Fluorescence Imaging of Proteins and Essential Metals in Subcellular Neuronal Compartments

open access: yesChemical & Biomedical Imaging
Richard Ortega   +5 more
doaj   +1 more source

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