Results 231 to 240 of about 142,936 (307)

Redox-driven speciation and colloid formation contribute the in vivo chemistry and organ deposition of Astatine-211. [PDF]

open access: yesEJNMMI Radiopharm Chem
Dong X   +11 more
europepmc   +1 more source

In situ Generation of Fluoride Catalysts for CO2‐to‐Formic Acid Conversion With Silicon Reducing Agent

open access: yesChemistry – A European Journal, EarlyView.
Reductive conversion of CO2 to formic acid with waste silicon reducing agent catalyzed by in situ generation of active fluoride species from a tertiary amine, protonic acid, and simple inorganic fluoride salt, such as KF and NaF. ABSTRACT The activation and catalytic reduction of carbon dioxide (CO2) using silicon‐based reducing agents is an important ...
S. M. A. Hakim Siddiki   +6 more
wiley   +1 more source

Cyclen Tetra‐Amide Ligands as a Privileged Class of Ligands for Studying Second‐Sphere Coordination Environments

open access: yesChemistry – A European Journal, EarlyView.
Cyclen tetra‐amide derivatives provide a privileged ligand platform for controlling second‐coordination sphere structure. Hydrogen‐bond networks in the second‐coordination sphere are leveraged to stabilize a EuII‐containing cyclen tetra‐amide derivative in physiologically relevant conditions by limiting the access of O2, establishing a design‐principle
Andrea L. Batchev   +5 more
wiley   +1 more source

Impact of Organo‐Functionalization on the Light‐Driven Hydrogen Evolution Reactivity of Molecular Molybdenum Sulfides

open access: yesChemistry – A European Journal, EarlyView.
Organo‐functionalized molecular molybdenum sulfides were synthesized using bidentate N‐donor ligands and investigated as light‐driven homogeneous hydrogen evolution reaction (HER) catalysts. Trends observed in the HER activity of these catalysts were elucidated by combining photophysical, electrochemical and computational studies.
Moritz Jahn   +9 more
wiley   +1 more source

CactEcoDB: Trait, spatial, environmental, phylogenetic and diversification data for the cactus family. [PDF]

open access: yesSci Data
Thompson JB   +10 more
europepmc   +1 more source

Mechanochemical Amidation Mediated by 1,1’‐Oxalyldiimidazole for the Synthesis of Agrochemicals

open access: yesChemistry – A European Journal, EarlyView.
Mechanochemical amidation using 1,1'‐oxalyldiimidazole (ODI) overcomes limitations of 1,1’‐carbonyl diimidazole (CDI) as coupling agent by enabling the efficient mechanochemical synthesis of three marketed agrochemicals from deactivated carboxylic acids.
Andrea Casagrande   +6 more
wiley   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

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