Results 131 to 140 of about 42,210 (307)

Upcycling Water Pollutants Into Long‐Chain Polymers via Synergistic Interfacial Dechlorination and Organic Radical Stabilization

Angewandte Chemie, EarlyView.
HEO‐regulated electronic structure drives nonradical PI activation, promoting ETP‐mediated polymerization of 4CP into high‐molecular‐weight products with enhanced surface enrichment. Concurrent dechlorination occurs via radical coupling and •OHads attack, enabling efficient carbon retention and selective product evolution at the liquid–solid interface.
Ziwei Yao, Yidi Chen, Penghui Shao, Jian Liu, Xiaodan Wang, Kunsheng Hu, Xubiao Luo, Nanqi Ren, Xiaoguang Duan   +8 more
wiley   +2 more sources

Pyridine‐Isomerism‐Driven Spin Engineering at a COP‐Fe3O4 Interface for High‐Performance Oxygen Reduction Electrocatalysis

Advanced Energy Materials, EarlyView.
Strategically adjusting the pyridine nitrogen position in the polymer matrix (pyridine isomerism) intensifies its interaction with embedded Fe3O4 nanocrystals. This enhanced interaction induces a spin‐state transition in Fe from low‐spin to intermediate‐spin, accompanied by refined d‐orbital properties.
Ruiqi Cheng, Xiaodong Lin, Qi Li, Yueying Chu, Xia Li, Huihuang Fang, Lin Zeng, Xinlin Hong, Alexandru Vlad, Guangchao Li, Feng Deng, Kwok‐yin Wong   +11 more
wiley   +1 more source

Entropy‐Stabilized Aluminate Catalysts That Break the Activity–Stability Tradeoff in CF4 Hydrolysis

Angewandte Chemie, EarlyView.
Entropy‐stabilized aluminate breaks the activity–stability tradeoff in CF4 hydrolysis by combining a multication aluminate framework with an entropy‐stabilized lattice. An electron‐deficient Al–O environment is F‐philic but O‐phobic, enabling C–F activation while suppressing H2O poisoning. Under steam‐rich, strongly fluorinating conditions, the entropy‐
Seunghyuck Chi, Hyungmin Jeon, Yaejun Baik, DongHwan Oh, Jin Seok, Woosung Choi, Seungjun Lee, Minkee Choi   +7 more
wiley   +2 more sources

Complex Iridium Oxides Converge In Structure And Reactivity During Acidic Oxygen Evolution Electrocatalysis

Advanced Energy Materials, EarlyView.
Ir‐based double perovskites restructure during acidic oxygen evolution electrocatalysis through dissolution of non‐Ir cations and convergence toward IrOx active‐site motifs with similar structure and intrinsic activity across compositions. The identity of the dissolving cations controls dissolution and surface reconstruction kinetics, clarifying how ...
Harrison H. Lippie, Xun Zhan, Kevin C. Matthews, Arya M. Balasubramanian, Jamie H. Warner, Joaquin Resasco   +5 more
wiley   +1 more source

Atomistic Phase Transition Mechanism of Zero-Strain Electrode Material: Transmission Electron Microscopy Investigation of Li4Ti5O12 Spinel Lattice Upon Lithiation

The lithiation mechanism of electrode materials is important for understanding the basic reactions in Li-ion batteries. In particular, zero-strain materials have garnered interest owing to their stable charge–discharge performances.
Hiroyuki, Ozaki, Mitsunori, Kitta, Noboru, Taguchi, Tetsu, Kiyobayashi   +3 more
core   +1 more source

Electrical characterization by impedance spectroscopy of Zn7Sb2O12 ceramic

Materials Research, 2003
Impedance spectroscopy technique was used to investigate the electric properties of Zn7Sb2O12, an electroceramic with inverse spinel type structure. The electric characterization of the Zn7Sb2O12 semiconducting ceramic was performed at temperature from ...
Nobre Marcos A. de Lima, Lanfredi Silvania   +1 more
doaj  

Linking DSC/TGA to Cell Levels: Energetics, Evolved Gases, and Thermal Safety of NMC811‐Graphite Micro‐Cell

Advanced Energy Materials, EarlyView.
A bottom‐up, component‐resolved framework combining DSC/TGA, evolved gas analysis, and in situ XRD reveals how decomposition pathways control energy release in partial and micro‐cell configurations. Separator‐free assemblies are dominated by cathode‐O2${\rm O}_2$/anode‐Li reactions, while the separator restricts oxygen transport, reshapes the reaction ...
Ayrton M. Yanyachi, Lingmin Lin, Siddhartha Nanda, Wenlong Li, Yijin Liu, Steven Swinnea, Hadi Khani, Donal Finegan, Ofodike A. Ezekoye   +8 more
wiley   +1 more source

Synergistic Regulation of Interfacial Potential and Anionic Covalency for High‐Voltage Cobalt‐Free All‐Solid‐State Batteries

Angewandte Chemie, EarlyView.
A synergistic interface regulation strategy using high‐dielectric BaTiO3 and sulfate‐derived S─O bonds is developed to unlock high‐voltage LiNi0.5Mn1.5O4 all‐solid‐state batteries. By mitigating space‐charge layer effects and stabilizing lattice oxygen, the system achieves high‐rate (3 C) and durable operation in 5 V‐class cobalt‐free solid‐state ...
Yue Wang, Shuibin Tu, Long Qian, Shijie Xu, Chao Ye, Shi‐Zhang Qiao   +5 more
wiley   +2 more sources

Perimeter‐intensified inverse Zr‐Co oxygen carrier for biomass chemical‐looping gasification with high CO selectivity

AIChE Journal, EarlyView.
Abstract Chemical‐looping gasification (CLG) offers a promising route for renewable biomass valorization, yet conventional oxygen carrier regeneration with O₂/H₂O is energy‐intensive and often produces low‐quality syngas. Here, we develop an inverse ZrO2/Co3O4 oxygen carrier that enables selective biochar oxidation and efficient lattice‐oxygen transfer
Junling Gao, Haifeng Qi, Kun Lei, Tingwei Wang, Yijie Yang, Hongwei Li, Rongjun Zhang, Yu Wu, Canran Huang, Zhao Sun   +9 more
wiley   +1 more source

A Comprehensive Assessment and Benchmark Study of Large Atomistic Foundation Models for Phonons

Advanced Intelligent Discovery, EarlyView.
We benchmark six large atomistic foundation models on 2429 crystalline materials for phonon transport properties. The rapid development of universal machine learning potentials (uMLPs) has enabled efficient, accurate predictions of diverse material properties across broad chemical spaces.
Md Zaibul Anam, Ogheneyoma Aghoghovbia, Mohammed Al‐Fahdi, Lingyu Kong, Victor Fung, Ming Hu   +5 more
wiley   +1 more source