Results 141 to 150 of about 29,788 (277)

Engineering Na‐Rich P2‐Type Layered Oxides Through Li/Ti Dual Doping for Oxygen Redox Activation and Superior Structural Stability

open access: yesAdvanced Energy Materials, EarlyView.
P2‐type sodium layered oxides have potential for high‐voltage operation but suffer from structural instability and capacity fading. This work demonstrates that synergistic Li and Ti co‐doping enhances sodium inventory, suppresses detrimental phase transitions, and activates reversible lattice oxygen redox.
Rishika Jakhar   +16 more
wiley   +1 more source

Donor–Acceptor Pentacene Analogues With Near‐Infrared Emission and Tunable Aromaticity

open access: yesAngewandte Chemie, EarlyView.
Air‐ and photostable heterocyclic pentacene analogues with donor and acceptor groups flanking a para‐quinodimethane core exhibit large dipole moments, narrow bandgaps, reversible redox behavior, and NIR‐I to NIR‐II absorption and emission with pronounced solvatochromism.
Krzysztof Nowak   +6 more
wiley   +2 more sources

Square wave voltammetry of surface-active, electroinactive compounds [PDF]

open access: yes, 2008
Square wave voltammetry (SWV) is generally considered as being insensitive to capacitive currents, which is true if it is compared to alternating current voltammetry, but less so if the comparison is made to pulse and differential pulse voltammetry. In fact, the sensitivity of SWV to capacitive current depends on the frequency of signal.
Jadreško, Dijana   +2 more
openaire   +1 more source

Universal Oxychlorination Strategy in Halide Solid Electrolytes for All‐Solid‐State Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A WO2Cl2‐driven oxychlorination strategy enables bulk oxygen incorporation into close‐packed LixMCl6 (M = Zr, Y, Er, In) halide lattices. Oxygen is selectively anchored by W6+ as lattice‐integrated [WO2Cl4]2− units, regulating the anionic framework, diversifying Li coordination, and weakening Li–Cl interactions.
Jae‐Seung Kim   +13 more
wiley   +1 more source

Electroactive Metal–Organic Frameworks Enabling Unidirectional Electrochemical Capacitors and Logic Gates (MOF‐CAPode)

open access: yesAngewandte Chemie, EarlyView.
MOF‐CAPodes are introduced by pairing various p‐MOFs with an n‐MOF as electrode materials in a battery‐like assembly. The devices achieve high figures of merit (RRI = 23.5; RRII = 94.4%) and perform excellently in prototypical logic gates (AND, OR) highlighting a new direction for ionological systems based on electroactive MOFs.
Tim Engelhardt   +9 more
wiley   +2 more sources

Oxygen‐Driven Structural Reorganization by Trace Water Enabling Fast Li‐Ion Transport in a Pliable Solid Electrolyte

open access: yesAdvanced Energy Materials, EarlyView.
Trace water is acting as a constructive mediator in 2LiCl–GaF3, markedly increasing ionic conductivity while reorganizing local coordination. Hydration creates localized Li+ solvation environments and partially dissociates ion pairs, enhancing Li‐ion mobility.
Youngkyung Kim   +10 more
wiley   +1 more source

Controlling Near‐Infrared Fluorescence‐to‐Phosphorescence Ratios and Triplet Lifetimes in Rhodium(I) Dimers via Primary and Secondary Coordination Sphere Effects

open access: yesAngewandte Chemie, EarlyView.
RhI dimers with bridging aryl isocyanide and di‐phosphine ligands show NIR‐I or NIR‐II fluorescence/phosphorescence, depending on the ligands and conformational rigidity at the Rh2 core. Rh‐Rh interactions can be tuned by peripheral modification of the aryl isocyanide ligand, resulting in a rigid Rh2 core and improved photophysical properties ...
Vanitha R. Naina   +4 more
wiley   +2 more sources

Operando X‐Ray Diffraction and Total Scattering Characterization of Battery Materials: Not Just a Pretty Picture

open access: yesAdvanced Energy Materials, EarlyView.
This review focuses on operando studies of battery materials by X‐ray diffraction (XRD) and total X‐ray scattering (TXS). This work highlights potential pitfalls and identify best‐practices for operando studies and reviews some unusual experiments to illustrate how these methods can be applied beyond the evaluation of the early‐stage cycling mechanisms
Amalie Skurtveit   +5 more
wiley   +1 more source

Synthetic Surface Design of Transparent Electrodes for Enhanced Molecular Contact in Perovskite Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
A simple solution‐based ITO surface treatment unlocks the full potential of phosphonic‐acid SAMs by balancing surface hydroxylation, conductivity, and homogeneity. Moderately hydroxylated interfaces yield uniform, electronically favourable contacts, enhancing charge extraction, stability, and thermal‐cycling resilience, with broad applicability across ...
Rik Hooijer   +18 more
wiley   +1 more source

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