Results 171 to 180 of about 29,788 (277)

Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes

open access: yesChemistry – A European Journal, EarlyView.
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel   +5 more
wiley   +1 more source

Ordered Nanostructural Engineering of Cathode Catalyst Layer With High Mass Transport Efficiency for High‐Performance Ultra‐Low Pt Loading Proton Exchange Membrane Fuel Cells

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
An ordered cathode catalyst layer with efficient mass transport capability was developed based on the ALD of Pt onto VACNTs for high‐performance ultra‐low Pt loading PEMFC. The order‐structured cathode catalyst layer (CCL) has been considered the most promising solution to construct low‐cost proton exchange membrane fuel cells (PEMFCs) with an ultra ...
Jia Liu   +8 more
wiley   +1 more source

Simulation-Based Approach to Determining Electron Transfer Rates Using Square-Wave Voltammetry. [PDF]

open access: yesLangmuir, 2017
Dauphin-Ducharme P   +5 more
europepmc   +1 more source

Gold(I) Phosphine/Phosphido‐Borohydride Complexes

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair   +3 more
wiley   +1 more source

Rational Optimization of Self‐Reporting Alcohol‐Oxidizing RhIII$^{\mathrm{III}}$ Complexes

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
A series of four different [(NN)Rh(Cp*)X]n+$^{\mathrm{n+}}$ complexes (NN = chelating α$\alpha$‐diimine ligand, Cp* = pentamethylcyclopentadienyl, X = Cl, solvent) are reported which all do possess a colorimetric self‐reporting property upon alcohol oxidation formation of the Rh(I) state. Analysis of alcohol oxidation rates
Luca Hefty   +5 more
wiley   +1 more source

Recent Advances in the Laser‐Based Fabrication and Applications of High‐Entropy Alloy Nanoparticles

open access: yesMetalMat, EarlyView.
This review presents recent advances in the laser‐based fabrication of high‐entropy alloy nanoparticles, focusing on scalable, environmentally friendly, and compositionally tunable synthesis methods. It highlights the critical influence of laser parameters on nanoparticle size, phase, and morphology, enabling tailored properties for applications in ...
Bibek Kumar Singh   +4 more
wiley   +1 more source

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