Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel +5 more
wiley +1 more source
Single Voltammetric Sweep Calibration-Free Interrogation of Electrochemical Aptamer-Based Sensors Employing Continuous Square Wave Voltammetry. [PDF]
Abeykoon SW, White RJ.
europepmc +1 more source
Understanding Signal and Background in a Thermally Resolved, Single-Branched DNA Assay Using Square Wave Voltammetry. [PDF]
Somasundaram S, Holtan MD, Easley CJ.
europepmc +1 more source
An ordered cathode catalyst layer with efficient mass transport capability was developed based on the ALD of Pt onto VACNTs for high‐performance ultra‐low Pt loading PEMFC. The order‐structured cathode catalyst layer (CCL) has been considered the most promising solution to construct low‐cost proton exchange membrane fuel cells (PEMFCs) with an ultra ...
Jia Liu +8 more
wiley +1 more source
Simulation-Based Approach to Determining Electron Transfer Rates Using Square-Wave Voltammetry. [PDF]
Dauphin-Ducharme P +5 more
europepmc +1 more source
Gold(I) Phosphine/Phosphido‐Borohydride Complexes
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair +3 more
wiley +1 more source
Determination of carnosic acid in Rosmarinus officinalis L. using square wave voltammetry and electrochemical behavior. [PDF]
Yilmaz ÜT +3 more
europepmc +1 more source
Rational Optimization of Self‐Reporting Alcohol‐Oxidizing RhIII$^{\mathrm{III}}$ Complexes
A series of four different [(NN)Rh(Cp*)X]n+$^{\mathrm{n+}}$ complexes (NN = chelating α$\alpha$‐diimine ligand, Cp* = pentamethylcyclopentadienyl, X = Cl, solvent) are reported which all do possess a colorimetric self‐reporting property upon alcohol oxidation formation of the Rh(I) state. Analysis of alcohol oxidation rates
Luca Hefty +5 more
wiley +1 more source
Substituent Inductive Effects on the Electrochemical Oxidation of Flavonoids Studied by Square Wave Voltammetry and Ab Initio Calculations. [PDF]
Arroyo-Currás N +2 more
europepmc +1 more source
Recent Advances in the Laser‐Based Fabrication and Applications of High‐Entropy Alloy Nanoparticles
This review presents recent advances in the laser‐based fabrication of high‐entropy alloy nanoparticles, focusing on scalable, environmentally friendly, and compositionally tunable synthesis methods. It highlights the critical influence of laser parameters on nanoparticle size, phase, and morphology, enabling tailored properties for applications in ...
Bibek Kumar Singh +4 more
wiley +1 more source

