Results 241 to 250 of about 59,462 (310)

Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers

open access: yesAdvanced Materials, EarlyView.
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez   +9 more
wiley   +1 more source

Tuning Amorphous‐Crystalline Catalytic Interfaces by Mechanochemistry: Cu‐Based Metallic Glasses Coupled with Ceria for CO Oxidation

open access: yesAdvanced Materials, EarlyView.
Ball‐milling Cu‐based metallic glasses with ceria creates a unique nanostructure where metallic glass particles are wrapped by CeO2 nanoparticles. The intimate integration triggers copper state reorganization during reaction and aging, boosting CO oxidation and COPrOx activity.
Maahin Mirzay‐Shahim   +17 more
wiley   +1 more source

Ultrafast Terahertz Field Control of the Emergent Magnetic and Electronic Interactions at Oxide Interfaces

open access: yesAdvanced Materials, EarlyView.
Intense single‐cycle THz electric‐field pulses enable ultrafast control of emergent electronic and magnetic states at LaNiO3/CaMnO3 interfaces. Combined X‐ray and optical probes reveal sub‐picosecond demagnetization driven by spin‐polarized currents and slower magnetoelastic dynamics linked to spin–lattice coupling.
Abigail M. Derrico   +15 more
wiley   +1 more source

Additive Manufacturing of Molecular Architecture Encoded Stretchable Polyethylene Glycol Hydrogels and Elastomers

open access: yesAdvanced Materials, EarlyView.
Bottlebrush molecular architecture prevents the crystallization of high molecular weight polyethylene glycol (PEG) based polymers, enabling highly stretchable photocurable PEG hydrogels and elastomers for high‐performance conductive solvent‐free electrolytes at room temperature and for additive manufacturing of complex architectures and multi‐material ...
Baiqiang Huang   +5 more
wiley   +1 more source

POM‐Based Water Splitting Catalyst Under Acid Conditions Driven by Its Assembly on Carbon Nanotubes

open access: yesAdvanced Materials, EarlyView.
A newly‐engineered POM‐based electrocatalyst incorporating non‐innocent counter cations exhibits fast kinetics for either the OER or HER under strongly acidic conditions (1 m H2SO4), depending on whether it is assembled on carbon nanotubes (1@CNT) or physically mixed with them (1/CNT). In water‐splitting tests using a two‐electrode setup, these systems
Eugenia P. Quirós‐Díez   +8 more
wiley   +1 more source

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