Results 81 to 90 of about 30,772 (337)

Tuning the Electronic Structure and Spin State of Fe─N─C Catalysts Using an Axial Oxygen Ligand and Fe Clusters for High‐Efficiency Rechargeable Zinc–Air Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A FeN4─O/Clu@NC‐0.1Ac catalyst containing atomically‐dispersed FeN4─O sites (medium‐spin Fe2+) and Fe clusters delivered a half‐wave potential of 0.89 V for ORR and an overpotential of 330 mV at 10 mA cm−2 for OER in 0.1 m KOH. When the catalyst was used in a rechargeable Zn–air battery, a power density of 284.5 mW cm−2 was achieved with excellent ...
Yongfang Zhou   +8 more
wiley   +1 more source

Utilização da múltipla voltametria de onda quadrada na determinação eletroanalítica de compostos orgânicos e inorgânicos Use of the multiple square wave voltammetry in the electroanalytical determination of organic and inorganic compounds

open access: yesQuímica Nova, 2007
This paper reports the development of multiple square wave voltammetry and the possibilities of its use for electroanalytical determinations of organic and inorganic compounds with the improvement of the signal-to-noise ratios and detection limits 2-3 ...
Djenaine De Souza   +4 more
doaj   +1 more source

Electrochemistry of uranium in molten LiF–CaF2 [PDF]

open access: yes, 2012
This article is focused on the electrochemical behaviour of U ions in molten LiF–CaF2 (79–21 wt.%) eutectic. On aWelectrode, U(III) is reduced in one step to U metal and U(III) can be also oxidised to U(IV). Both systems were studied by cyclic and square
Chamelot, Pierre   +5 more
core   +3 more sources

Powering the Future: A Cobalt‐Based Catalyst for Longer‐Lasting Zinc–Air Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A novel N‐doped graphitic shell‐encapsulated Co catalyst reveals superior bifunctional ORR/OER activity in alkaline media, empowering outstanding liquid and quasi‐solid‐state ZAB activity. The system delivers long‐term durability, a peak power density of 127 mW cm−2 and successfully powers an LED and a mini fan.
Manami Banerjee   +10 more
wiley   +1 more source

Nano molar detection of acyclovir, an antiviral drug at nanoclay modified carbon paste electrode

open access: yesSensing and Bio-Sensing Research, 2017
A nano level voltammetric sensing method has been developed for determination of acyclovir (ACV) at nano clay modified carbon paste sensor by employing cyclic voltammetry (CV) and square wave voltammetry (SWV) techniques in pH5.0.
Nagaraj P. Shetti   +3 more
doaj   +1 more source

A new insight into the oxidative mechanism of caffeine and related methylxanthines in aprotic medium: May caffeine be really considered as an antioxidant? [PDF]

open access: yes, 2018
Background: Antioxidant properties have been recently suggested for caffeine that seems showing protective effects against damages caused by oxidative stress. In particular, a HO% scavenging activity has been ascribed to caffeine. Even if the oxidation
Curulli, Antonella   +3 more
core   +1 more source

Mesoporous Carbon Thin Films with Large Mesopores as Model Material for Electrochemical Applications

open access: yesAdvanced Functional Materials, EarlyView.
Mesoporous carbon thin films possessing 70 nm mesopores are prepared on titanium substrates by soft templating of resol resins with a self‐synthesized poly(ethylene oxide)‐block‐poly(hexyl acrylate) block copolymer. A strategy to avoid corrosion of the metal substrate is presented, and the films are extensively characterized in terms of morphology ...
Lysander Q. Wagner   +9 more
wiley   +1 more source

Simulation of square wave voltammetry of three electrode reactions coupled by two reversible chemical reactions

open access: yesJournal of Electrochemical Science and Engineering, 2017
Three fast and reversible electrode reactions that are connected by two reversible chemical reactions that are permanently in the equilibrium are analysed theoretically for square wave voltammetry.
Milivoj Lovrić
doaj   +1 more source

MATHCAD – a Tool for Numerical Calculation of Square-Wave Voltammograms [PDF]

open access: yes, 1999
An alternative approach for numerical calculation of the square-wave voltammograms using the mathematical programming package MATHCAD is presented. A quasi-reversible redox reaction is considered and a mathematical model is developed under conditions ...
Gulaboski, Rubin, Mirceski, Valentin
core  

Polymeric foams as the matrix of voltammetric sensors for the detection of catechol, hydroquinone, and their mixtures [PDF]

open access: yes, 2018
Producción CientíficaPorous electrodes based on polymethylmethacrylate and graphite foams (PMMA_G_F) have been developed and characterized. Such devices have been successfully used as voltammetric sensors to analyze catechol, hydroquinone, and their ...
Fernández Blanco, C.   +4 more
core   +1 more source

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