Zinc/Silver-Based Hydrogen Sulfide Trapping as an Alternative to Cadmium for Sulfur Stable Isotope Analysis. [PDF]
Ure D +3 more
europepmc +1 more source
Entropy‐Stabilized Aluminate Catalysts That Break the Activity–Stability Tradeoff in CF4 Hydrolysis
Entropy‐stabilized aluminate breaks the activity–stability tradeoff in CF4 hydrolysis by combining a multication aluminate framework with an entropy‐stabilized lattice. An electron‐deficient Al–O environment is F‐philic but O‐phobic, enabling C–F activation while suppressing H2O poisoning. Under steam‐rich, strongly fluorinating conditions, the entropy‐
Seunghyuck Chi +7 more
wiley +1 more source
CSF protein clearance impairment revealed using stable isotope kinetics in normal pressure hydrocephalus. [PDF]
Leckey CA +21 more
europepmc +1 more source
Heterogeneous iron‐catalyzed environmentally benign and sustainable CH‐oxidative esterification methodology has been developed for the synthesis of esters. This challenging reaction has been achieved by the rational design of specific single atom iron‐based catalyst with Fe‐N4 active centers, which empowered the oxidative esterification of methyl and ...
Zhuang Ma +8 more
wiley +1 more source
Protocol to assess retinal metabolic flux of mice via stable isotope-resolved metabolomics. [PDF]
Komissarov G +8 more
europepmc +1 more source
Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement
Supramolecular confinement redirects the excited‐state proton transfer pathway of an amphoteric emitter. In water, the molecule undergoes ESPD, whereas co‐assembly with γ‐cyclodextrin forms nanotubes that template slip‐stacked emitter pairs and enable ESIMPT. Structural and photophysical characterization of the assemblies shows that the preorganization
Luis C. Pantaleone +8 more
wiley +1 more source
Stable isotope insights into water use sources and adaptation strategies of Tamarix Chinensis in desert ecotone of arid regions. [PDF]
Liu L +6 more
europepmc +1 more source
Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration
The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti +9 more
wiley +1 more source
Stable isotope evidence for the participation of commoners in Inka khipu production. [PDF]
Hyland S +4 more
europepmc +1 more source

