Results 231 to 240 of about 375,375 (306)

Hyperpolarization of Molecular Deuterium

open access: yesAngewandte Chemie, EarlyView.
Hyperpolarized molecular deuterium is generated and detected using a nonhydrogenative SABRE catalyst with nicotinamide. The resonance shows a strongly enhanced partially negative line, substrate‐dependent and sensitive to transient intermediates.
Theresa L. K. Hune   +5 more
wiley   +1 more source

Biosynthesis of Kaitocephalin: A Neuroprotective Natural Product Featuring a Peptide‐Like yet Nonpeptidic Scaffold

open access: yesAngewandte Chemie, EarlyView.
Kaitocephalin (KCP) is a neuroprotective fungal metabolite with a unique scaffold of amino acids linked via C–C bonds. Genome‐transcriptome analyses identified its biosynthetic gene cluster (kpb cluster) in Eupenicillium shearii. LC‐MS/MS profiling identified four new KCP‐related compounds.
Yukari Maeno   +5 more
wiley   +1 more source

Beyond Hydrogen Bonding: π···π Stacking Directed Self‐Assembly of Carboxylic Acid Clusters in the Gas Phase

open access: yesAngewandte Chemie, EarlyView.
A critical transformation from hydrogen‐bonded trimers to π–π stacked tetramers is unveiled by microwave spectroscopy, highlighting dispersion as a key force in directing carboxylic acid aggregation. ABSTRACT Carboxylic acids critically influence atmospheric chemistry by modulating acidity, new particle formation, and aerosol growth.
Jingling Hong   +3 more
wiley   +1 more source

Metabolomic profiling and stable isotope tracing of human schwannomas: A novel perspective on tumor biology and radiation response. [PDF]

open access: yesNeurooncol Adv
Dougherty MC   +7 more
europepmc   +1 more source

Tailoring Electronic Properties of Precision Graphene Nanoribbons via Nanopore Engineering

open access: yesAngewandte Chemie, EarlyView.
Novel porous graphene nanoribbons incorporating [18]annulene nanopores, together with a nonporous GNR of identical width, have been synthesized. Spectroscopic and theoretical analyses reveal that nanopore incorporation effectively tunes their electronic properties by enlarging the bandgap, reducing charge‐carrier mobility, and modulating exciton ...
Kun Liu   +19 more
wiley   +1 more source

Quantification and Localisation of New Brain Lipid Synthesis Using Deuterium Oxide and High Resolution Mass Spectrometry

open access: yesAngewandte Chemie, EarlyView.
Liquid chromatography tandem mass spectrometry and mass spectrometry imaging were used in combination with deuterium oxide administration to quantify and localise newly synthesised myelin lipids in the mouse brain. This methodology, used here to show sites of myelin repair, enables the measurement of dynamic lipid synthesis in living systems and ...
Catherine Zhang   +7 more
wiley   +1 more source

Factors associated with protection from MASLD in type 2 diabetes: A prospective study integrating longitudinal MRI/MRE and stable isotope tracing. [PDF]

open access: yesJHEP Rep
Tavaglione F   +8 more
europepmc   +1 more source

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