Results 191 to 200 of about 223,864 (297)

Photocatalytic Asymmetric C‐C Coupling for CO2 Reduction on Cu‐Zn Bimetallic Catalysts with Dipole‐Limiting Effects

open access: yesAdvanced Science, EarlyView.
Asymmetric Cu–Zn dual sites on EDTA‐grafted Ti‐MOF amplify the dipole‐limiting domain field (DLDF), facilitating C–C coupling. This strategy yields an exceptional C2H4 production rate of 308.72 µmol g−1 h−1 with 98.4% electron selectivity in photocatalytic CO2 reduction, highlighting the potential of asymmetric site engineering and local field ...
Peidong Ma   +8 more
wiley   +1 more source

Intramolecular Synergy of CO2 Activation and H Spillover on Heteronuclear Dual‐Metal Phthalocyanine Assemblies for Selective CO2 Photoreduction

open access: yesAdvanced Science, EarlyView.
The CuNiPc/BiVO4 heterojunction is designed and synthesized for selective CO2 photoreduction. The cascade interfacial Z‐scheme charge transfer and the intramolecular synergy of Cu–Ni dual sites on CO2 activation and H spillover contribute to the high photocatalytic performance and selectivity. ABSTRACT Solar‐driven CO2 conversion holds great promise in
Ye Liu   +10 more
wiley   +1 more source

Synergetic Relay Between Atomic Hydrogen and Chlorine Radicals Enables Efficient Nitrate‐to‐Nitrogen Gas Conversion

open access: yesAdvanced Science, EarlyView.
Using photoelectrochemical (PEC) deep denitrification technology, a novel synergistic reduction‐oxidation process enables efficient conversion of nitrate (NO3−) to nitrogen (N2), while suppressing key intermediate ammonium (NH4+) and toxic nitrite (NO2−) accumulation.
Yongjie Wang   +11 more
wiley   +1 more source

Tree-ring stable isotopes from the European Alps reveal long-term summer drying over the Holocene. [PDF]

open access: yesSci Adv
Arosio T   +12 more
europepmc   +1 more source

Ultrafast Electron Transfer Coupled with a Proton Relay in an Anisotropic Dual S‐Scheme Heterojunction for Overcoming Kinetics Mismatch in H2O2 Photosynthesis

open access: yesAdvanced Science, EarlyView.
An anisotropic dual S‐scheme heterojunction (C3N4/SubPc‐1/C3N5) is constructed to overcome the electron–proton kinetics mismatch in photocatalytic H2O2 production. The imide bridge serves as a dual channel for ultrafast electron transfer and proton relay, synergistically enabling efficient dual‐pathway oxygen reduction and achieving a high H2O2 ...
Bing Wang   +7 more
wiley   +1 more source

Single‐Atom Cobalt Species on Curved Hollow Carbon Sphere: Breaking Linear Scaling Relationship Limitations in Electrocatalytic Deactivation of Dilute Antibiotic Pollutants

open access: yesAdvanced Science, EarlyView.
A cobalt (Co)‐SACs consisting of single‐atom Co anchored on a nitrogen‐doped hollow porous carbon sphere (Co1/N‐HCS) is fabricated for electrocatalytic hydrodechlorination of dilute antibiotics. The hollow porous architecture of N‐HCS concentrates the antibiotics, while its curved surface promotes proton transfer at the Co1 site via localized electric ...
Jiahong Zou   +8 more
wiley   +1 more source

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