Results 101 to 110 of about 5,604 (251)

Organic Photoelectrochemical Cells Beyond Performance: Interface and Catalyst Engineering for Durability

open access: yesAdvanced Energy Materials, EarlyView.
Organic photoelectrochemical cells based on π‐conjugated semiconductors offer a versatile platform for solar fuel generation. This review outlines operating principles, device architectures, and key metrics, and highlights advances in p‐ and n‐type photoelectrodes, interfacial engineering, and catalyst integration.
Jaehyeong Kim   +8 more
wiley   +1 more source

Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations

open access: yesAngewandte Chemie, EarlyView.
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera   +2 more
wiley   +2 more sources

Data on Stark Broadening of N V Spectral Lines

open access: yesData
A data set on Stark broadening parameters defining the Lorentzian line profile (spectral line widths and shifts) for 31 multiplets of four-times-charged nitrogen ion (N V), with lines broadened by impacts with electrons (e), protons (p), He II ions, α ...
Milan S. Dimitrijević   +2 more
doaj   +1 more source

Strain‐Directed Ru Redistribution to Form RuO2/Pt Mosaic Heterointerfaces for Acid‐Stable Water Oxidation

open access: yesAdvanced Energy Materials, EarlyView.
Strain‐driven Ru inward migration creates confined RuO2/Pt mosaic heterointerfaces within a PtNi multiframe. These interfaces enable redox‐asymmetric Pt–Ru coupling that stabilizes Ru4+, suppresses lattice oxygen participation, and promotes highly durable acidic oxygen evolution.
Yeji Park   +13 more
wiley   +1 more source

Enzyme‐Like Synthetic Cleft for Light‐Driven Water‐Oxidation Catalysis Via an Oxide Relay Pathway

open access: yesAngewandte Chemie, EarlyView.
A carboxylic acid group introduced into the second coordination sphere of a Ru(bda) water oxidation catalyst forms a defined hydrogen bond within the catalytic cleft. This interaction locks the group in place and enables an intramolecular oxide relay pathway between Ru(V)═O and the carboxylate group, providing a distinct and efficient route for O─O ...
Daniel A. P. Friedewald   +7 more
wiley   +2 more sources

Silicon‐Based Anodes for Sulfide Solid‐State Batteries: Failure Mechanisms and Multiscale Design Strategies

open access: yesAdvanced Energy Materials, EarlyView.
Silicon anodes in sulfide SSBs face coupled electrochemo‐mechanical failure by interface instability. This review examined recent advances and proposed mitigation strategies via material‐, electrode/interface‐, and cell‐level‐ engineering. We further evaluate scalable synthesis of sulfide SEs.
Murugesan Karuppaiah   +4 more
wiley   +1 more source

Synergistic Lewis Acid Photocatalysis Over Cluster‐Defect‐Engineered UiO‐66 for Efficient Liquid Biomass Upgrading

open access: yesAngewandte Chemie, EarlyView.
A cluster‐defect engineering strategy is presented for the rational design of Zn‐incorporated UiO‐66 photocatalysts. Selective acid etching mediates hierarchical porosity and abundant Lewis acid sites, tailoring the electronic structure and enhancing light harvesting.
Hao Wang   +6 more
wiley   +2 more sources

In Situ Evolution of Artificial Interphase Enabling Stable, High‐Performance Lithium Metal Batteries

open access: yesAdvanced Energy Materials, EarlyView.
An evolutionary artificial interphase is presented for stable lithium metal batteries. A Mg3N2‐based layer spontaneously evolves into a hybrid interphase enriched with superionic Li3N and lithiophilic Mg‐Li alloy during cycling. This dynamic, self‐reinforcing mechanism effectively suppresses dendrite growth and enables exceptional long‐term cycling ...
Sangcheol Lee   +4 more
wiley   +1 more source

Entropy‐Stabilized Aluminate Catalysts That Break the Activity–Stability Tradeoff in CF4 Hydrolysis

open access: yesAngewandte Chemie, EarlyView.
Entropy‐stabilized aluminate breaks the activity–stability tradeoff in CF4 hydrolysis by combining a multication aluminate framework with an entropy‐stabilized lattice. An electron‐deficient Al–O environment is F‐philic but O‐phobic, enabling C–F activation while suppressing H2O poisoning. Under steam‐rich, strongly fluorinating conditions, the entropy‐
Seunghyuck Chi   +7 more
wiley   +2 more sources

CrossMatAgent: AI‐Assisted Design of Manufacturable Metamaterial Patterns via Multi‐Agent Generative Framework

open access: yesAdvanced Intelligent Discovery, EarlyView.
CrossMatAgent is a multi‐agent framework that combines large language models and diffusion‐based generative AI to automate metamaterial design. By coordinating task‐specific agents—such as describer, architect, and builder—it transforms user‐provided image prompts into high‐fidelity, printable lattice patterns.
Jie Tian   +12 more
wiley   +1 more source

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