Experimentally-based Fe-catalyzed ethene oligomerization machine learning model provides highly accurate prediction of propagation/termination selectivity. [PDF]
Chem SciYang B +6 more
europepmc +1 more source
Magnetic DNA Origami Nanorotors
Advanced Materials, EarlyView.Magnetic actuation is a powerful and broadly applicable actuation mechanism due to its programmability and compatibility with biological entities. Here we demonstrate magnetic DNA origami nanorotors (MADONAs) by assembling magnetic nanocubes on DNA origami.
Lennart J. K. Weiß +13 more
wiley +1 more source
True Closed‐Loop Recyclable Hydrogels Enabled by Imine Boronic Ester Crosslinking
Advanced Materials, EarlyView.Subtle molecular differences in imine boronic ester crosslinkers profoundly influence hydrogel properties. 2‐formylphenylboronic acid crosslinkers form previously undisclosed 3‐amino‐benzoxaborole heterocycles, enhancing elasticity despite lower crosslinking density compared to their 4‐formylphenylboronic acid counterparts.
Jenna A. King +5 more
wiley +1 more source
Advanced Materials, EarlyView.Asymmetric lamellar templating at the perovskite/C60 interface is achieved using a laterally polarized indole spacer. Surface anchoring and Ind–Ind assembly form a π‐rich lamellar interphase that supports uniform C60 contact formation, suppresses recombination, preserves electron extraction, and enables certified high‐efficiency cells and modules with ...
Taeyoon Ki +16 more
wiley +1 more source
Escaping the Scaling Relationships in Oxygen Reduction Catalysis: Implications for PEM Fuel Cells
Advanced Materials, EarlyView.Escaping the scaling relationships of the oxygen reduction reaction is vital for hydrogen fuel cells. This outlook examines how interfacial heterogeneity, spanning the subsurface lattice, chemisorption layer, and near‐interface solvation volume, mechanistically decouples intermediate binding energetics.
Muhammad Bilal Wazir +2 more
wiley +1 more source
Interpreting terminal selectivity in undirected C(sp<sup>3</sup>)-H functionalization: kinetic insights and mechanistic implications. [PDF]
Chem SciTu JL, Guo L, Huang B, Xia W.
europepmc +1 more source
From Payload‐First Toward Dual‐Mechanism Antibody–Drug Conjugates
Advanced Materials, EarlyView.Conjugation converts potent antibodies into underexposed carriers. This perspective defines the antibody exposure deficit and maps a mechanism‐first design space from payload‐first to antibody‐first ADC architectures, integrating DAR, linker chemistry, and Fc engineering to guide rational design of constructs that balance targeted cytotoxicity with ...
Xavier Pivot +3 more
wiley +1 more source
Recent Advances in Coordination-Insertion Copolymerization of Ethylene with Polar Monomers Catalyzed with Pd and Ni Complexes. [PDF]
Polymers (Basel)Hu S, Zhou Y, Hu H, Mao G, Xin S.
europepmc +1 more source
Chloride Ions: Essential Agents for Achieving Spontaneous Delamination of MXene
Advanced Materials, EarlyView.This work first identifies chloride ions as essential agents for spontaneous MXene delamination. Without Cl−, etched Ti3C2Tx remains multilayered; with Cl−, interlayer modification enables Li+ intercalation and osmotic swelling. The SPEED process couples HF‐assisted Al extraction, Cl−‐mediated interlayer expansion, and Li+‐driven swelling to produce ...
Sukhyeun Jang +11 more
wiley +1 more source
Mimetics of in-cell and subcellular crowding and solvation for protein folding. [PDF]
Biochem Soc TransKnab E, Tahir U, Davis CM.
europepmc +1 more source