Results 151 to 160 of about 4,537,291 (248)

Modular One‐Pot Access to π‐Expanded Tetrakis(Phenothiazinyl)‐Silanes With Broadly Tunable Redox and Emission Properties

open access: yesChemistry – A European Journal, EarlyView.
A library of 21 tetrakis(phenothiazinyl)‐substituted silanes with broadly variable substituent decoration, which are fully reversible multistage redox systems with intense tunable emission from deep blue to yellow–green (441–533 nm), was rapidly synthesized by bromine–lithium exchange/borylation–Suzuki coupling of tetrakis(4‐bromophenyl)silane or by ...
Thomas P. M. Merke   +4 more
wiley   +1 more source

π‐Extended Salphen Scaffolds Enable CO2 Electroreduction and Singlet Oxygen Generation

open access: yesChemistry – A European Journal, EarlyView.
New family of π‐extended salen ligands bearing phenylene bridge and tunable phenyl‐based substituents, and their corresponding boron difluoride complexes. Thanks to the extended π‐delocalization over the molecule, the ligands themselves show promising results in electrochemical CO2 reduction to CO, while the complexes act as efficient photosensitizers ...
Vincenzo Langellotti   +10 more
wiley   +1 more source

New Insights into Poly(Dichlorophosphazene) Synthesis via Me3Si─N═PCl3 Polymerization: An Experimental and Theoretical Study

open access: yesChemistry – A European Journal, EarlyView.
Poly(dichlorophosphazene) synthesis via Me3Si─N═PCl3 polymerization was reinvestigated using quantum chemical calculations and experiments. A cationic initiator (Ph3PCl2) enables ambient‐temperature polymerization through chloride‐catalyzed cationic pathways involving dissociation, nucleophilic chloride attack, and chain‐propagating species formation ...
Cornelius Knuth   +6 more
wiley   +1 more source

Substituent‐Dependent SERS Kinetics of Citrate‐Stabilized Gold Nanoparticles: Balancing Hotspot Formation and Colloidal Flocculation

open access: yesChemistry – A European Journal, EarlyView.
Reporter chemistry controls the operational window of liquid‐phase SERS. Para‐substituted benzenethiols induce distinct AuNPs colloidal regimes, ranging from delayed but stable hotspot formation to rapid flocculation‐dominated signal decay. The balance between SERS‐active‐state formation and colloidal loss defines whether a reporter provides reliable ...
Irene Calderon Gonzalez   +2 more
wiley   +1 more source

Benzo[c][1,2,5]Thiadiazole Linkers Enhance the Effectiveness of Cavity‐Containing Supramolecular Photocatalysts

open access: yesChemistry – A European Journal, EarlyView.
Seven novel supramolecular photosensitizers based on benzo[c][1,2,5]thiadiazole (BTZ) tethered to calix[4]arene (C[4]) scaffolds are reported with facile, scalable, and selective syntheses. Their abilities to produce singlet oxygen have been tested through the photo‐oxidation of α‐terpinene.
Leonardo Amicosante   +6 more
wiley   +1 more source

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