Results 251 to 260 of about 681,467 (332)

Enhanced Selectivity of Chalcogen Bonding over Halogen Bonding Catalyzed C‐glycosylation Through Differentiated Intermediate Activation

Angewandte Chemie, EarlyView.
By harnessing chalcogen bonding (ChB) catalysis, an exclusive access into a highly stereoselective strain‐release C‐glycosylation pathway was discovered. This was surprisingly not replicable by the conceptually similar halogen bonding (XB) catalysis.
Hao Guo, Charles C. J. Loh
wiley   +2 more sources

Literary case study of psychosis: <i>The Vegetarian</i>. [PDF]

World J Psychiatry
Ungvari GS, Caroff SN, Csihi L, Gazdag G.   +3 more
europepmc   +1 more source

Homoleptic Bismuth Alkynes: Isolable Reagents for Selective Alkynyl Radical Transfer

Angewandte Chemie, EarlyView.
The first series of fully characterized homoleptic alkynyl bismuth compounds Bi(C≡CR)3 is presented. Facile homolytic Bi–C bond cleavage grants access to alkynyl radicals, which have been employed in selective C–X bond formation (X = C, B, Se, Te). This complements existing strategies for alkynyl radical generation as it proceeds under mild and purely ...
Gargi Kundu, Felix Debbeler, Sascha Reith, Frerik Wurm, Alicia Casitas, Crispin Lichtenberg   +5 more
wiley   +2 more sources

Momentum-dependent scaling exponents of nodal self-energies measured in strange metal cuprates and modelled using semi-holography. [PDF]

Nat Commun
Smit S, Mauri E, Bawden L, Heringa F, Gerritsen F, van Heumen E, Huang YK, Kondo T, Takeuchi T, Hussey NE, Allan M, Kim TK, Cacho C, Krikun A, Schalm K, Stoof HTC, Golden MS.   +16 more
europepmc   +1 more source

Solvation Entropy as a Lever for Steering the Macroscopic Properties of a Functional Supramolecular Helical Polymer

Angewandte Chemie, EarlyView.
The structural transition between the two fully‐characterized states of a supramolecular helical hydrogen‐bonded polymer (represented as blue and light pink stacks) can be predictably varied over 85 K by changing the nature and amount of cosolvent; entropy of solvation (schematized as solvents of different sizes) is the main lever to tune the ...
Huanjun Kong, Mayte A. Martínez‐Aguirre, Yan Li, Tomoyuki Ikai, Eiji Yashima, Gangamallaiah Velpula, Steven De Feyter, Pierre‐Antoine Albouy, Komivi Akpo, Patrick Brocorens, Roberto Lazzaroni, Laurent Bouteiller, Matthieu Raynal   +12 more
wiley   +2 more sources

Superagers Resist Typical Age-Related White Matter Structural Changes. [PDF]

J Neurosci
Garo-Pascual M, Zhang L, Valentí-Soler M, Strange BA.   +3 more
europepmc   +1 more source

Transferring Porosity Across Physical States Using Metal–Organic Cages: Porous Liquids, Glasses, Rubbers, and More

Angewandte Chemie, EarlyView.
Discrete porous metal–organic cages provide a platform to extend porosity beyond crystalline solids. Their peripheral functionality governs inter‐cage interactions and physical state, enabling preservation of intrinsic porosity across liquids, glasses, and rubbers.
Francisco Sánchez‐Férez, Arnau Carné‐Sánchez, Daniel Maspoch   +2 more
wiley   +2 more sources

Unfolding Hidden Narratives: Glimpses of an Ethos of Senses in a Dementia-Care Facility. [PDF]

Hastings Cent Rep
van Wijngaarden E.
europepmc   +1 more source

Stepwise Reduction of Ruthenium and Growth of Magnetic Structure During Hydrothermal Crystallisation of SrRu2O6 from KRuO4

Angewandte Chemie, EarlyView.
In situ neutron powder diffraction data collected while heating the Ru(VII) reagent KRuO4 in the presence of aqueous Sr2+ reveal the crystallisation of a Ru(VI) oxyhydroxide before the expected Ru(V) oxide; at the same time evolution of antiferromagnetism in the final SrRu2O6 product follows the growth of its crystal structure.
Mark Crossman, Craig I. Hiley, Helen Y. Playford, Chris M. Goodway, Ronald I. Smith, Thomas C. Hansen, Richard I. Walton   +6 more
wiley   +2 more sources

Living with congenital heart disease: a qualitative study to explore psychosocial impacts in adulthood. [PDF]

Int J Cardiol Congenit Heart Dis
Lloyd L, Ruban S, Badal T, Strange G, Celermajer DS, Bonner C.   +5 more
europepmc   +1 more source