Results 221 to 230 of about 29,739 (303)

Superbasic Anionic Calcium Alkyl Complexes: Templated Twofold Deprotonation of Benzene. [PDF]

open access: yesAngew Chem Int Ed Engl
Lim LF   +6 more
europepmc   +1 more source

Superatom Distortion Induces Triferroicity and Spin Splitting in Two‐Dimensional Antiferromagnets

open access: yesAdvanced Science, EarlyView.
The incorporation of superatoms into a 2D square lattice induces symmetry breaking, thereby enabling concurrent coupling among magnetism, ferroelectricity, and ferroelasticity. This strategy achieves triferroic behavior—characterized by spin‐split antiferromagnetic ground states—and offers a viable pathway toward energy‐efficient spintronic devices ...
Zhen Gao   +6 more
wiley   +1 more source

Rigid‐Flexible Coupling Units Enable Robust Large Birefringence

open access: yesAdvanced Science, EarlyView.
A rigid–flexible coupling strategy, combining flexible (S3)2− linear units with rigid (VO4)3− tetrahedra, yields Sr4(VO4)2S3—a robust crystal exhibiting large birefringence (Δn = 0.52@550 nm) and remarkable thermal, air, and water stability. ABSTRACT Birefringent crystals are central to polarization control in laser technologies (e.g., wave plates and ...
Jie Zhou   +8 more
wiley   +1 more source

Unsaturated Coordination Oxygen in Zn─V─O Vacancy Clusters Enables Superb Zinc Storage Capability

open access: yesAdvanced Science, EarlyView.
Zn3(VO4)2 with Zn─V─O vacancy clusters was synthesized and innovatively applied as cathode material in aqueous Zn‐ion batteries. In‐situ XRD, HRTEM and ab initio molecular dynamics simulations unveil the double reaction mechanism of zinc ions. Adsorption of zinc ions on unsaturated coordination O and H+ on O in ‐VO4 contributes to the main capacity. It
Yulong Chi   +8 more
wiley   +1 more source

Unraveling the Synergistic Activity‐Stability Enhancement of a High‐Entropy Perovskite Air Electrode for Dual Ceramic Electrochemical Cells

open access: yesAdvanced Science, EarlyView.
A high‐entropy air electrode material, Gd0.2Pr0.2Ba0.2Sr0.2Ca0.2FeO3−δ (GPBSCF), is developed for both solid oxide fuel cells and reversible protonic ceramic cells. Its enhanced activity stems from increased oxygen vacancies/holes. The stability improvement is attributed to lattice distortion, while thermal expansion reduction is synergistically due to
Ying Zhang   +9 more
wiley   +1 more source

In situ atomic-resolution imaging of water vapor-driven multistep oxidation dynamics in strontium cobaltite. [PDF]

open access: yesSci Adv
Yang Z   +10 more
europepmc   +1 more source

Multifunctional Eutectic Mixtures Enable Integrated Recovery of U, Pu, and Sr From Nuclear Waste

open access: yesAdvanced Science, EarlyView.
A novel class of multifunctional eutectic mixtures, crafted from crown ether and organophosphorus molecules, achieves highly efficient, simultaneous recovery of uranium, plutonium, and strontium from nuclear waste. The material operates via a dual “coordination‐encapsulation” mechanism within self‐assembled reverse‐micelle structures, offering a ...
Yifan Wang   +8 more
wiley   +1 more source

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