Results 181 to 190 of about 100,451 (291)

1,3‐Brook Rearrangement of α‐Silyl Allylic Alcohols: Copper‐Catalyzed Enantiospecific Formation of Allenes and Copper‐Mediated ipso‐Substitution Reactions Affording Trisubstituted Alkenes

open access: yesAngewandte Chemie, EarlyView.
A regioselective ruthenium catalyzed trans‐hydrosilylation of propargyl alcohols followed by a 1,3‐Brook rearrangement opens access to reactive organocopper intermediates, which evolve upon warming into allenes with strict chirality transfer to the emerging axis; alternatively, these reactive species can be trapped with a large variety of electrophiles
Jack L. Sutro   +3 more
wiley   +2 more sources

Photochemical Reaction Discovery Enabled by the Dynamic Speciation of Copper Complexes

open access: yesAngewandte Chemie, EarlyView.
A strategy for accelerated photochemical reaction discovery is reported that harnesses the dynamic speciation of copper complexes, driven by their labile metal–ligand bonds. This platform simplifies reaction screening by combining an earth‐abundant copper(II) salt with commercially available ligands, which reversibly generate multiple catalytic species
Alessio Regni   +6 more
wiley   +2 more sources

On‐Demand Deconstructable Thermosets Through Cleavable Comonomer and Thermolatent Base Synergy

open access: yesAngewandte Chemie, EarlyView.
Thermosets, valued for their chemical and mechanical properties, resist recycling due to their cross‐linked structure. Weak bonds via comonomers enable degradability, but diffusion limits effectiveness. We incorporate thermolatent bases before polymerization (thermal or 3D‐VAT printing).
Sophia Kouider   +15 more
wiley   +2 more sources

Solvent- and Hydrogen-Free Upcycling of Polystyrene by Layered Double Oxides. [PDF]

open access: yesSmall
Zhu Z   +10 more
europepmc   +1 more source

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