Borylcyclopropanes: Synthetic Strategies and Applications
Angewandte Chemie, EarlyView.Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
Chemical Recycling of Post-Consumer Polystyrene by Thermal Pyrolysis: High-Yield Recovery of Aromatic Hydrocarbons for Circular Plastic Economy. [PDF]
Polymers (Basel)Hernandez-Fernandez J +2 more
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Polymer Brushes Govern Defect‐Selective Oxidative Etching of Penta‐Twinned Gold Nanorods
Angewandte Chemie, EarlyView.Polymer brushes act as active interfacial regulators of oxidative etching, directing it to crystallographic defects. In penta‐twinned gold nanorods, defect–ligand interplay localizes etching to defect regions and induces surface corrugations on the long nanorod sides. This work establishes a framework for programmable nanoengineering of the surfaces of
Tianyi Wu +9 more
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Designing Soft and Transparent Films Based on Multi-Phase Polypropylene Copolymers and Styrene Block Copolymers. [PDF]
Polymers (Basel)Gahleitner M +4 more
europepmc +1 more source
Dual Activation of H2 and CO2 by a Pincer‐Type Ni–Zn Heterobimetallic Complex
Angewandte Chemie, EarlyView.A bimetallic Ni−Zn complex performs sequential activations of H2 (1 equiv) and CO2 (2 equiv). This bimetallic cooperativity is attributed to the weak Lewis acidic nature of Zn(II), which promotes fluxional ligand binding. Namely, an X‐type ligand at Ni, where X is hydride or formate, toggles between two different binding modes: bridging Zn(μ‐X)Ni and ...
Krishnendu Dey +3 more
wiley +2 more sources
Hydrophobic modification of a polyurethane sponge <i>via</i> emulsion polymerization for selective oil-water separation. [PDF]
RSC AdvIslam Setu MA +5 more
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1,4-Pentanediol as an Alternative Biomass-Derived Medium for the Phosphine-Free Heck Coupling Reactions. [PDF]
ChemSusChemÁrvai C, Mika LT.
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Unveiling the Mechanistic Role of Lewis Acidic Ionic Liquids in Styrene Polymerization. [PDF]
ACS Polym AuAraruna T +5 more
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Whole-genomic and transcriptomic analyses elucidate <i>p</i>-cresol and styrene degradation metabolism in <i>Rhodococcus opacus</i> 1CP. [PDF]
Appl Environ MicrobiolKumaran S +9 more
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