Results 221 to 230 of about 317,842 (407)

CO2‐to‐Cyclic Carbonate Transformation at Ambient Pressure Using a Mechanochemically Prepared Ti(III) Catalyst

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A Ti(III) complex synthesized mechanochemically catalyzes the cycloaddition of CO2 (1 bar) with terminal, internal, and trisubstituted epoxides. Mechanistic studies by density functional theory calculations reveal that the superior activity of Ti(III) compared to Ti(IV) arises from its lower oxophilicity, facilitating CO2 insertion into Ti–O bonds, as ...
Elena Álvarez‐Ruiz   +5 more
wiley   +1 more source

Biobased Ligands Enable Catalysis with Base Metals

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Biobased ligands unlock versatile catalytic transformations, including Cu‐catalyzed hydroboration of olefins and borylation of alkyl halides, Fe‐catalyzed ketone hydrogenation, and Ni‐catalyzed terminal alkyne dimerization. First‐row transition metal catalysis has already reshaped organic synthesis, offering more abundant and cost‐effective ...
Raju Yalla, Ashot Gevorgyan
wiley   +1 more source

Assessing microplastic contamination in milk and dairy products. [PDF]

open access: yesNPJ Sci Food
Visentin E   +4 more
europepmc   +1 more source

Bio‐Inspired Polymer Nanoreactor: Integrating Hemin Coordination and Micellar Confinement for Catalysis in Water

open access: yesAdvanced Sustainable Systems, EarlyView.
This study develops an amphiphilic copolymer nanocarrier (P(His‐r‐Sty)‐b‐PDMAA) for aqueous hemin catalysis, enabling efficient styrene cyclopropanation (94.4% yield, 0.3 mol% hemin) with excellent recyclability (>90% activity after 4 cycles), overcoming solubility and microenvironment challenges.
Lulu Chen   +4 more
wiley   +1 more source

Styrene Aziridination by Iron(IV) Nitrides.

open access: yesAngewandte Chemie, 2015
Salvador B. Muñoz   +7 more
semanticscholar   +1 more source

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