Results 301 to 310 of about 317,842 (407)

Effect of perfluoroacrylate ratio on the generation of stable superhydrophobic surfaces displaying low contact angle hysteresis [PDF]

open access: yes, 2005
Acatay, Kazım   +5 more
core  

Enantioselective Alkoxycarbonyl‐Lactonization of Alkenes via the Merger of Photoredox and Copper Catalysis

open access: yesAdvanced Science, EarlyView.
A highly enantioselective alkoxycarbonyl‐lactonization of alkenes is reported through a photoredox/copper dual‐catalyzed alkoxycarbonyl radical addition/cyclization reaction. Abstract The synthesis of ester derivatives represents one of the most significant and fundamental tasks in modern organic chemistry, and numerous methods have been developed in ...
Yuping Xiong   +5 more
wiley   +1 more source

XFEL crystallography reveals catalytic cycle dynamics during non-native substrate oxidation by cytochrome P450BM3. [PDF]

open access: yesCommun Chem
Nagao S   +14 more
europepmc   +1 more source

Decoupling Electron and Proton Transfer in Noncontact Catalytic Hydrogenation of Nitroaromatics

open access: yesAdvanced Science, EarlyView.
A noncontact catalytic system is constructed by modifying metal nanoparticles supported on conductive carbon with (hypo)phosphorous acid. This design effectively prevents the adsorption of unsaturated substrates while permitting H2 activation to generate electrons and protons. The hydrogenation is governed by electron transfer processes, which occur at
Zhongyin Liang   +3 more
wiley   +1 more source

Direct Carboboration of Aryl Alkenes with Stable Organoborons Through Ziegler‐Type Addition

open access: yesAdvanced Science, EarlyView.
The direct carboboration of vinyl arenes with benzylic boronates has been achieved using KOtBu as the catalyst. Vinylcyclopropanes and vinylcyclobutane also participate in this reaction, yielding the corresponding 1,5‐ and 1,6‐carboboration products.
Mo Yang   +5 more
wiley   +1 more source

Selective Aerobic Peroxidation of Styrene Catalyzed by a Cobalt <i>tert</i>-Butylperoxo Complex. [PDF]

open access: yesJACS Au
Chen Y   +8 more
europepmc   +1 more source

Inspired by Reinforced‐Concrete Structures: High‐Strength, Stable, Sustainable Reed‐Based Plastics

open access: yesAdvanced Science, EarlyView.
Inspired by the structure of reinforced concrete, which develops a composite with high‐strength, stability, fire resistance, and nontoxicity, by using the regular and continuous of reed fiber and thermoset tannin‐based resin. This composite demonstrates potential as a sustainable alternative to conventional petroleum‐derived plastics, with promising ...
Yuhui Huang   +7 more
wiley   +1 more source

Electro‐Thermally Controlled Active Mechanical Metamaterials with Programmable Stiffness and Nonreciprocity

open access: yesAdvanced Science, EarlyView.
Actively programmable mechanical metamaterial, featuring smart conductive polymers, designed instabilities, and compliant mechanisms. Capable of stiffness switching, local surface pressure modulation, and nonreciprocal shear relationships that allow local shielding from surface traction. Potential applications in soft robotic grippers and smart medical
Jai Dunne   +5 more
wiley   +1 more source

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