Effect of perfluoroacrylate ratio on the generation of stable superhydrophobic surfaces displaying low contact angle hysteresis [PDF]
Acatay, Kazım+5 more
core
A highly enantioselective alkoxycarbonyl‐lactonization of alkenes is reported through a photoredox/copper dual‐catalyzed alkoxycarbonyl radical addition/cyclization reaction. Abstract The synthesis of ester derivatives represents one of the most significant and fundamental tasks in modern organic chemistry, and numerous methods have been developed in ...
Yuping Xiong+5 more
wiley +1 more source
XFEL crystallography reveals catalytic cycle dynamics during non-native substrate oxidation by cytochrome P450BM3. [PDF]
Nagao S+14 more
europepmc +1 more source
Decoupling Electron and Proton Transfer in Noncontact Catalytic Hydrogenation of Nitroaromatics
A noncontact catalytic system is constructed by modifying metal nanoparticles supported on conductive carbon with (hypo)phosphorous acid. This design effectively prevents the adsorption of unsaturated substrates while permitting H2 activation to generate electrons and protons. The hydrogenation is governed by electron transfer processes, which occur at
Zhongyin Liang+3 more
wiley +1 more source
Iron Porphyrins and Iron Salens as Highly Enantioselective Catalysts for the Ring-Expansion Reaction of Epoxides to Tetrahydrofurans. [PDF]
Ulutürk M+3 more
europepmc +1 more source
Direct Carboboration of Aryl Alkenes with Stable Organoborons Through Ziegler‐Type Addition
The direct carboboration of vinyl arenes with benzylic boronates has been achieved using KOtBu as the catalyst. Vinylcyclopropanes and vinylcyclobutane also participate in this reaction, yielding the corresponding 1,5‐ and 1,6‐carboboration products.
Mo Yang+5 more
wiley +1 more source
Selective Aerobic Peroxidation of Styrene Catalyzed by a Cobalt <i>tert</i>-Butylperoxo Complex. [PDF]
Chen Y+8 more
europepmc +1 more source
Inspired by Reinforced‐Concrete Structures: High‐Strength, Stable, Sustainable Reed‐Based Plastics
Inspired by the structure of reinforced concrete, which develops a composite with high‐strength, stability, fire resistance, and nontoxicity, by using the regular and continuous of reed fiber and thermoset tannin‐based resin. This composite demonstrates potential as a sustainable alternative to conventional petroleum‐derived plastics, with promising ...
Yuhui Huang+7 more
wiley +1 more source
Design and Synthesis of Fe<sub>3</sub>O<sub>4</sub>-Loaded Polymer Microspheres with Controlled Morphology: Section II Fabrication of Walnut-like Superparamagnetic Polymer Microspheres. [PDF]
Acha F, Scheff T, DiazArmas N, Zhang J.
europepmc +1 more source
Actively programmable mechanical metamaterial, featuring smart conductive polymers, designed instabilities, and compliant mechanisms. Capable of stiffness switching, local surface pressure modulation, and nonreciprocal shear relationships that allow local shielding from surface traction. Potential applications in soft robotic grippers and smart medical
Jai Dunne+5 more
wiley +1 more source