Results 171 to 180 of about 6,792 (286)

Identification of HOTf-Driven Brønsted Acid Catalysis in the AuCl₃/AgOTf System for the Hydroalkylation of Styrene. [PDF]

Inorg Chem
Mahdian A, Nikonovich T, Kaabel S, Laasonen K, Farshadfar K.   +4 more
europepmc   +1 more source

Monolithic Porous Polymer Architectures for Visible‐to‐UV Upconversion‐Driven Photochemical Reactions

Angewandte Chemie, EarlyView.
Porous polymer monoliths embedded with sensitizer–annihilator dye pairs enable efficient solid‐state visible‐to‐ultraviolet triplet–triplet annihilation‐based photon upconversion under low‐intensity blue and green light. Their co‐continuous porous architectures balance chromophore interactions with substrate accessibility, providing robust and tunable ...
Sakura Nakagawa, Naoto Matsumoto, Masanori Uji, Maria‐Sophie Bertrams, Christoph Kerzig, Nobuhiro Yanai   +5 more
wiley   +2 more sources

A biocatalytic platform for the stereoselective synthesis of diverse atropisomeric compounds using engineered metalloenzymes. [PDF]

Sci Adv
Cai X, Cui D, Chu Y, Rui Y, Duan X, Peng Y, Wang Z, Xu J.   +7 more
europepmc   +1 more source

Exclusive Hydroformylation of Terminal Olefins: A Phosphorus‐Free Ruthenium System for the Selective Functionalization of Complex Mixtures

Angewandte Chemie, EarlyView.
Development of a phosphorus‐free Ru/DBU catalyst enabling highly chemo‐ and regioselective hydroformylation of terminal olefins, sparing internal double bonds. Optimization of reaction parameters, ligand effects, and substrate scope including industrial feedstocks was realized.
Mohamed Niyaz Vellala Syed Ali, Ida Ziccarelli, Dilver Peña Fuentes, Christoph Kubis, Robert Franke, Ralf Jackstell, Matthias Beller   +6 more
wiley   +2 more sources

Titanium‐Catalyzed Defluorination of Poly(Vinyl Fluoride) and Poly(Vinylidene Fluoride) Under Friedel–Crafts Conditions

Angewandte Chemie, EarlyView.
Cationic titanium sandwich catalysts display exceptional activity in the hydrodefluorination of Csp3─F bonds, in the presence of silanes and aromatic solvents (turnover numbers up to 3000). As a result, they can be used to defluorinate challenging fluoropolymers, such as poly(vinyl fluoride) (PVF) or poly(vinylidene fluoride) (PVDF).
Louis Le Moigne, Marie Sircoglou, Quentin Bonnin, Marie‐José Penouilh, Joan Vignolle, Etienne Grau, Cédric Le Coz, Mélanie Bousquet, Paul Fleurat‐Lessard, Adrien T. Normand   +9 more
wiley   +2 more sources

<i>cis</i>-Selective Direct Halocyclopropanation of Alkenes Mediated by Nucleophilic Cobalt Photocatalysis. [PDF]

JACS Au
Teye-Kau JHG, Pauze M, Pitre SP.
europepmc   +1 more source

β-Substituted Styrenes in Heteroaryl-Directed Hydroalkylative Cross-Couplings: Regio-, Diastereo-, and Enantioselective Formation of β-Stereogenic Tertiary Alcohols. [PDF]

J Am Chem Soc
Mao W, Robertson CM, Bower JF.
europepmc   +1 more source

Advances in Ligand Development for Wacker-Type Oxidation. [PDF]

ACS Omega
Zeng X, Chen L, Wang W, Zhang J, Meng Z.
europepmc   +1 more source

Visible-light-enabled three-component carboamidation of alkenes with aryl thianthrenium salts. [PDF]

Chem Sci
Feng K, Li X, Wang Y, Zheng L, Lv J, Shi Y, Yang D.   +6 more
europepmc   +1 more source

Remote Desaturation of Unprotected Amines and C─H Amination of Alkanes by Polarity‐Matched N‐Radical Cations

Angewandte Chemie, EarlyView.
Highly electrophilic N‐radical cations enable efficient and selective H‐atom transfer (HAT) of unprotected amines. In this exceedingly practical strategy, simple CuCl catalyzes an interrupted Hofmann–Löffler–Freytag (HLF) reaction to afford δ desaturated amines, aza‐heterocycles, and C─H aminated alkanes without protecting groups.
Pavitra Laohapaisan, Ross M. Dare, Meredith L. Rudich, Jacob J. A. Garwood, Siyuan Gong, R. Thomas Simons, David A. Nagib   +6 more
wiley   +1 more source