Bismuth-photocatalysed Heck-type coupling with alkyl and aryl electrophiles. [PDF]
Ni S +3 more
europepmc +1 more source
Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
wiley +1 more source
Formic Acid-Driven Rapid and Green Anti-Markovnikov Hydrothiolation of Styrenes
Rahul Upadhyay +3 more
doaj +1 more source
Fe-catalyzed efficient synthesis of 2,4- and 4-substituted quinolines via C(sp<sup>2</sup>)-C(sp<sup>2</sup>) bond scission of styrenes. [PDF]
Jagtap PA +3 more
europepmc +1 more source
Polymer Brushes Govern Defect‐Selective Oxidative Etching of Penta‐Twinned Gold Nanorods
Polymer brushes act as active interfacial regulators of oxidative etching, directing it to crystallographic defects. In penta‐twinned gold nanorods, defect–ligand interplay localizes etching to defect regions and induces surface corrugations on the long nanorod sides. This work establishes a framework for programmable nanoengineering of the surfaces of
Tianyi Wu +9 more
wiley +1 more source
Recent advances in copper-catalyzed direct hydroamination of alkenes with (hetero)aromatic amines. [PDF]
Lee H, Lee Y.
europepmc +1 more source
From Berzelius to Hyperspace: Previously Unrecognized Network of Reactivity in Textbook Brominations
Robotic scans across multidimensional condition spaces of classic bromination reactions uncover regions of previously unrecognized reactivity, yielding new major products and novel substitution patterns. Correlation and anticorrelation analyses of product distributions across these hyperspaces enable reconstruction of the underlying mechanistic ...
Yankai Jia +9 more
wiley +1 more source
Catalytic Asymmetric Ionic Hydrogenation of α-Alkyl Styrenes. [PDF]
Leinung W +5 more
europepmc +1 more source
TADF‐Active Tetrazole Luminophores for Visible‐Light Functionalization of Nanoparticles and Surfaces
A series of tetrazoles are reported that undergo 1,3‐dipolar cycloadditions with alkene and alkyne substrates, generating (dihydro)pyrazole products that exhibit thermally activated delayed fluorescence (TADF). The “photo‐click” reactivity of these tetrazoles is leveraged to functionalize nanoparticles and surfaces with TADF‐active chromophores ...
Ryoga Hojo +11 more
wiley +1 more source

