Results 251 to 260 of about 127,650 (334)

Rh-Catalyzed Enantioselective Aryl C-H Bond Cyclopropylation. [PDF]

open access: yesJ Am Chem Soc
Palomo E   +4 more
europepmc   +1 more source

Atroposelective Synthesis of Axially Chiral Styrenes via an Asymmetric C–H Functionalization Strategy

open access: yesCheM, 2020
Summary Axially chiral styrenes, which exhibit a chiral axis between a substituted alkene and an aromatic ring, have been largely overlooked. The hurdle is the lower barriers to rotation compared with that of their biaryl counterparts, rendering their ...
Han Yeqiang, Xin Hong, Qi-Jun Yao
exaly   +2 more sources
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Organo‐Mediator Enabled Electrochemical Deuteration of Styrenes

Angewandte Chemie - International Edition, 2023
Despite widespread use of the deuterium isotope effect, selective deuterium labeling of chemical molecules remains a major challenge. Herein, a facile and general electrochemically driven, organic mediator enabled deuteration of styrenes with deuterium ...
Tian Feng, Youai Qiu
exaly   +2 more sources

Atroposelective Access to Oxindole-Based Axially Chiral Styrenes via the Strategy of Catalytic Kinetic Resolution

Journal of the American Chemical Society, 2020
Atroposelective synthesis of axially chiral molecules has attracted substantial attention from chemists because of the importance of such molecules. However, catalytic asymmetric synthesis of axially chiral styrenes or vinyl arenes is underdeveloped and ...
Zhang Yu-Chen, Yinchun Jiao, Wei Tan
exaly   +2 more sources

Enantio- and Regioselective Ni-Catalyzed para-C-H Alkylation of Pyridines with Styrenes via Intermolecular Hydroarylation.

Journal of the American Chemical Society, 2022
Direct asymmetric functionalization of the pyridyl C-H bond represents a longstanding challenge in organic chemistry. We herein describe the first enantioselective para-C-H activation of pyridines through the use of a Ni-Al bimetallic catalyst system and
Junning Ma   +3 more
semanticscholar   +1 more source

Nickel-catalyzed Enantioselective Hydroarylation and Hydroalkenylation of Styrenes

open access: yesJournal of the American Chemical Society, 2019
We have developed a Ni-catalyzed enantioselective hydroarylation of styrenes with arylboronic acids using MeOH as the hydrogen source, providing an efficient method to access 1,1-diarylalkanes, which are essential structural units in many biologically ...
Yue-Gang Chen, Bin Shuai, Xuetao Xu
exaly   +2 more sources

Atroposelective Synthesis of Conjugated Diene-Based Axially Chiral Styrenes via Pd(II)-Catalyzed Thioether-Directed Alkenyl C-H Olefination.

Journal of the American Chemical Society, 2021
The efficient stereoselective synthesis of conjugated dienes, especially those with axial chirality, remains a great challenge. Herein, we report the highly atroposelective synthesis of axially chiral styrenes with a conjugated 1,3-diene scaffold via a ...
Liang Jin   +4 more
semanticscholar   +1 more source

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