Engineering Polar Nanoregions in COFs via Controlled Symmetry Breaking Toward Piezocatalysis
Polar nanoregions (PNRs) are engineered within covalent organic frameworks via asymmetric grafting of highly polar polyfluoroalkyl chains, which enables controlled symmetry breaking. These randomly oriented artificial PNRs dynamically respond to mechanical stimuli and impart relaxation behavior to the COFs (TFB‐TAPT‐FA).
Ge Yan +13 more
wiley +2 more sources
Developing Polymer Semi-Solid-State Gel Electrolyte with High-Performance Aqueous Zn-Mn Battery-Type Hybrid Capacitor Device for MnO<sub>2</sub>-MWCNT Cathode. [PDF]
Thirumal V, Rajivgandhi P, Kim J.
europepmc +1 more source
Enhanced Long-Term Barrier and Corrosion Protection of Epoxy Coatings Modified With Silica Nano-Oil. [PDF]
Zhou H +9 more
europepmc +1 more source
Boosting Charge Storage in Ferri/Ferrocyanide‐Based Alkaline Redox Flow Batteries
By modifying the solvation environment, cation engineering through Li+ substitution of traditional K+ or Na+ boosts the alkaline solubility of the ferri/ferrocyanide catholyte redox couple, providing a viable pathway to overcome the long‐standing challenge of energy density limitations for aqueous redox flow batteries (RBFs).
Mahla Sarfaraz Khabbaz +6 more
wiley +1 more source
Time-optimized ultrasonic synthesis of α-MnO<sub>2</sub> nanoflower: controlling structural evolution and agglomeration for stable electrochemical performance. [PDF]
Divyalekshmi SV +3 more
europepmc +1 more source
To address the unresolved challenge of selective bromide removal from reverse‐osmosis permeate, we developed benzothiazole‐functionalized COF/rGO electrodes that exploit directional chalcogen bonding to preferentially capture Br− over Cl−. The mesoporous BTzTp@rGO electrode achieved a maximum Br− uptake of 36.7 mg g−1, a Br−/Cl− selectivity factor of ...
Najat Maher Aldaqqa +7 more
wiley +2 more sources
Composition-Driven Structural Regulation of Fe-Co Aerogels for High-Current-Density Hydrogen Evolution. [PDF]
Kim SH, Choi H, Kim Y, Kim T, Park HH.
europepmc +1 more source
A Descriptor for Non‐Arrhenius Ion Transport Enables Design of Sulfide Superionic Conductors
A curated database of sulfide electrolytes reveals widespread non‐Arrhenius ion transport. Meyer–Neldel deviation (MND) quantifies this behavior, distinguishes low‐conductivity and superionic regimes, and guides composition screening. An experimentally validated candidate exhibits room‐temperature conductivity of 7.21 mS cm−1, an apparent activation ...
Han Zhou +6 more
wiley +1 more source
Engineering an Ni<sub>9</sub>S<sub>8</sub>@Fe-NiP-O<sub>2</sub> core-shell catalyst: high activity and stability for oxygen/hydrogen evolution in alkaline and ammonia-containing media. [PDF]
Zhao K +9 more
europepmc +1 more source
Mesopore geometry programs the working‐state interface of Fe single sites during nitrate electroreduction. Hexagonal channels reorganize interfacial water and accompany the reversible evolution of isolated Fe─O4‐like sites toward Fe─O─Fe‐like motifs, promoting successive hydrogenation toward NH3 with a Faradaic efficiency of 99.1%.
Xiangyang Liu +8 more
wiley +1 more source

