Results 161 to 170 of about 155,235 (338)

Alkyl Bismuth Cations: Synthesis, Characterization, and Application as Z‐Type Ligands

Chemistry – A European Journal, EarlyView.
Rare examples of alkyl bismuth cations [BiR2(SbF6)] are presented, including cyclopropyl ligands and a bismacyclic structure. The bismuth‐centered Lewis acids act as Z‐type ligands toward the electron‐rich platinum atom in [Pt(PCy3)2], generating a set of metal‐only Lewis pairs. The structural and spectroscopic properties of these rare types of bismuth
Johannes Schwarzmann, Joel Nitzsche, Cissie Slopianka, Liva Hartmann, William Augustinov, Alexandre Gagnon, Carsten von Hänisch, Crispin Lichtenberg   +7 more
wiley   +1 more source

Modular Design of Vacuum Systems for Lyophilization. [PDF]

Ind Eng Chem Res
Stratta L, Kadambi RP, Pasero L, Burcat SJ, Braatz RD, Trout BL, Slocum AH, Pisano R.   +7 more
europepmc   +1 more source

Sustainable Synthesis of 4,7‐Dihydro‐4,7‐ethano‐2H‐isoindoles—Key Building Blocks to Benzoporphyrins

Chemistry – A European Journal, EarlyView.
A facile and sustainable route to isoindole derivatives—key benzoporphyrin precursors—brings high‐ and low‐symmetry benzoporphyrins closer to practical application. ABSTRACT Benzoporphyrins, π extended porphyrin analogues, exhibit remarkable potential for optoelectronic and theragnostic applications, yet have remained largely confined to fundamental ...
Lampros Pascal Gazetas, Michael Ruppel, Christoph Richtzenhain, Frank Hampel, Norbert Jux, Dominik Lungerich   +5 more
wiley   +1 more source

Determination and Validation of Standard Enthalpies of Formation and Sublimation of Potassium Salts Using Solution Calorimetry and Quantum-Chemical Calculations. [PDF]

ChemistryOpen
Amanollahi Z, Zaitsau DH, Müller K, Bokareva OS, Siewert R.   +4 more
europepmc   +1 more source

Microspacing In-Air Sublimation Growth of Organic Crystals

, 2018
Xin Ye, Yang Liu, Quanxiang Han, Chao Ge, Shuangyue Cui, Leilei Zhang, Xiaoxin Zheng, Guangfeng Liu, Jie Liu, Duo Liu, X. Tao   +10 more
semanticscholar   +1 more source

S‐Doped Carbon Nitride Thin Films From a Triazole Precursor

Carbon Innovation, EarlyView.
Sulfur‐functionalized carbon nitride thin films are synthesized via low‐temperature chemical vapor deposition using a triazole‐derived precursor. Tunable sulfur incorporation modulates electronic and optical properties and enables efficient visible‐light photocatalysis with high conversion and selectivity.
Yen‐Han Wang, Enis Oğuzhan Eren, Baris Kumru, Paolo Giusto   +3 more
wiley   +1 more source

Development of a Mechanically Regenerating Desublimator for Freeze‐Drying Systems in the Food Industry

Chemie Ingenieur Technik, EarlyView.
Thermal defrosting limits desublimator efficiency in freeze‐drying. This review and case study compares thermal versus mechanical regeneration, links frost properties and external heat transfer to energy demand, and summarizes pilot‐scale scraping results enabling single‐unit, continuous lyophilization.
Moritz Krummenacher, Mirko Kleingries, Edgar Zimmer, Roman Blättler   +3 more
wiley   +1 more source

Experimental Study on the Influence of Different Loading Weights and Placement Forms on Vacuum Sublimation-Rehydration Thawing of Large Yellow Croaker. [PDF]

Foods
Sun Y, Wu W, Chen S, Xu N, Liu F, Xue A.
europepmc   +1 more source

Optimal model‐based design of experiments for parameter precision: Supercritical extraction case

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study investigates the process of chamomile oil extraction from flowers. A parameter‐distributed model consisting of a set of partial differential equations is used to describe the governing mass transfer phenomena in a cylindrical packed bed with solid chamomile particles under supercritical conditions using carbon dioxide as a solvent ...
Oliwer Sliczniuk, Pekka Oinas
wiley   +1 more source

Sublimation aides and abets co-milling and discoloration involving quinhydrone. [PDF]

Front Chem
Ezekiel CI, MacGillivray LR.
europepmc   +1 more source