Results 91 to 100 of about 363,660 (280)

Quantitative Analysis of Substituent Effects in Cu(II) and Co(II) Benzimidazole Complexes: Stability Constants Determined via Acetate-Mediated Synthesis and Benesi–Hildebrand Method Correlated with Hammett σ Parameters

Chemistry
This study presents a quantitative investigation of substituent effects on the stability of 1:2 complexes formed between para-substituted 2-phenylbenzimidazole ligands and Cu(II) or Co(II) ions.
Zoltán Köntös, Flóra Stedra, Viktória Ngo Hang   +2 more
doaj   +1 more source

17O NMR Spectra of α,β-Unsaturated Carbonyl Compounds RCH=CHCOX: the Influence of Group X on the δ(17O) Value of the Carbonyl Oxygen and on the Shielding Effect of Group R

Molecules, 1999
17O NMR spectra of RCOX (R = Me, Ph), RCH=CHCOX (R = H, Ph, Me, CO2Et) and Me2C=CHCOX (X = H, Me, Et, i-Pr, t-Bu, Ph, PhCH=CH, OMe, OEt, Cl, CN, CF3, CO2Et) are reported.
Jin-Cong Zhuo
doaj   +1 more source

Reaction and substituent constants for pyramidal inversion [PDF]

Tetrahedron Letters, 1973
Splitter, Janet S., Calvin, Melvin.
openaire   +2 more sources

Engineering an Artificial Metalloenzyme for Efficient Photo‐Enzymatic CO2 Conversion

Advanced Science, EarlyView.
We built a light‐driven artificial metalloenzyme by covalently conjugating formate dehydrogenase (FDH) with a tailored rhodium complex (Rh‐L6) to overcome spatial‐separation‐limited electron transfer. This integration boosts NADH regeneration and CO2 conversion, giving 2.31‐fold higher formate yield than physical mixtures, due to a narrowed bandgap and
Mengxue Kang, Yan Chu, Zhichun Xu, Jiao Feng, Ganlu Li, Kequan Chen, Hui Li   +6 more
wiley   +1 more source

Synthesis, Electrochemistry and Density Functional Theory of Osmium(II) Containing Different 2,2′:6′,2″-Terpyridines

Molecules
In coordination chemistry, 2,2′:6′,2″-terpyridine is a versatile and extensively studied tridentate ligand. Terpyridine forms stable complexes with a variety of metal ions through coordination sites provided by the three nitrogen atoms in its pyridine ...
Nandisiwe G. S. Mateyise, Marrigje M. Conradie, Jeanet Conradie   +2 more
doaj   +1 more source

H1N1 2009 pandemic influenza virus: resistance of the I223R neuraminidase mutant explained by kinetic and structural analysis.

PLoS Pathogens, 2012
Two classes of antiviral drugs, neuraminidase inhibitors and adamantanes, are approved for prophylaxis and therapy against influenza virus infections. A major concern is that antiviral resistant viruses emerge and spread in the human population. The 2009
Erhard van der Vries, Patrick J Collins, Sebastien G Vachieri, Xiaoli Xiong, Junfeng Liu, Philip A Walker, Lesley F Haire, Alan J Hay, Martin Schutten, Albert D M E Osterhaus, Steve R Martin, Charles A B Boucher, John J Skehel, Steve J Gamblin   +13 more
doaj   +1 more source

Self‐Healing Pd(II) Cage Metallogels for Iodine Capture in Water and Heterogeneous Photocatalysis

Advanced Science, EarlyView.
Two carbazole‐derived metal‐organic cages hierarchically self‐assemble into supramolecular metallogels that integrate autonomous self‐healing, reversible stimuli responsiveness, high‐capacity aqueous iodine capture, and visible‐light‐driven photocatalytic sulfide oxidation within a single multifunctional platform.
Monotosh Dalapati, Raghunath Singha, Debashree Manna, Dipak Samanta   +3 more
wiley   +1 more source

Determination of Gene‐Level Fitness Contributions Across the Mucin‐Utilization Network of Bacteroides thetaiotaomicron

Advanced Science, EarlyView.
Genome‐wide CRISPRi and RNA‐seq resolve how B. thetaiotaomicron converts host mucosal glycans into fitness. The study reveals a layered mucin‐utilization architecture in which capsular polysaccharides constrain surface access, extracellular CAZymes and peptidases show functional redundancy, and intracellular catabolic pathways create discrete metabolic
Kangsan Kim, Jiwon Lee, Minjeong Kang, Sung Sun Yim, Donghui Choe, Byung‐Kwan Cho   +5 more
wiley   +1 more source

Mode‐Resolved Phonon Dynamics Under Chemical Pressure in SnTe Thermoelectrics

Advanced Science, EarlyView.
Chemical pressure reshapes low‐energy optical phonons in SnTe, altering their dispersion and scattering with heat‐carrying acoustic modes. Positive and negative pressure states modify phonon frequencies and lifetimes in distinct ways, revealing how mode‐selective lattice perturbations regulate acoustic–optical interactions and suppress lattice thermal ...
Zhihao Li, Jianhong Hu, Panpan Peng, Peng Cao, Hui Zhang, Yujie Zong, Yanhui Wu, Hongchao Wang   +7 more
wiley   +1 more source

Sigma Hole Potentials as Tools: Quantifying and Partitioning Substituent Effects

Empirical substituent constants, such as the Hammett parameters, have found important utility in organic and other areas of chemistry. They are useful both in predicting the impact of substitutions on chemical processes and in rationalizing after-the ...
Kelling J. Donald (1613794), Nam Pham (688467), Pranav Ravichandran (17422746)   +2 more
core   +2 more sources