Results 191 to 200 of about 9,469,736 (295)
Engineering an Artificial Metalloenzyme for Efficient Photo‐Enzymatic CO2 Conversion
Advanced Science, EarlyView.We built a light‐driven artificial metalloenzyme by covalently conjugating formate dehydrogenase (FDH) with a tailored rhodium complex (Rh‐L6) to overcome spatial‐separation‐limited electron transfer. This integration boosts NADH regeneration and CO2 conversion, giving 2.31‐fold higher formate yield than physical mixtures, due to a narrowed bandgap and
Mengxue Kang +6 more
wiley +1 more source
Self‐Healing Pd(II) Cage Metallogels for Iodine Capture in Water and Heterogeneous Photocatalysis
Advanced Science, EarlyView.Two carbazole‐derived metal‐organic cages hierarchically self‐assemble into supramolecular metallogels that integrate autonomous self‐healing, reversible stimuli responsiveness, high‐capacity aqueous iodine capture, and visible‐light‐driven photocatalytic sulfide oxidation within a single multifunctional platform.
Monotosh Dalapati +3 more
wiley +1 more source
Inductive or Field Substituent Effect? Quantum Chemical Modeling of Interactions in 1-Monosubstituted Bicyclooctane Derivatives. [PDF]
ACS Omega, 2017 Szatylowicz H, Siodła T, Krygowski TM.
europepmc +1 more source
Advanced Science, EarlyView.The cooling process during the solid‐state synthesis of sodium manganese oxides governs oxygen‐mediated reconstruction. Slow cooling promotes a stacking‐fault‐rich framework that suppresses Mn migration, mitigates O2 release, and stabilizes oxygen redox with reduced voltage hysteresis.
Seungmin Lee +12 more
wiley +1 more source
Advanced Science, EarlyView.A dianionic ligand designed to encourage metal‐phosphine coordination—bis((3,5‐dimethylphenyl)amidomethyl)tertbutylphosphine (ArBiAMPtBu)—was employed in the synthesis of paramagnetic complexes of Ce, Nd, Np, and Pu, producing MI(ArBiAMPtBu)(thf)3.
Novan A. G. Gray +9 more
wiley +1 more source
Advanced Science, EarlyView.Genome‐wide CRISPRi and RNA‐seq resolve how B. thetaiotaomicron converts host mucosal glycans into fitness. The study reveals a layered mucin‐utilization architecture in which capsular polysaccharides constrain surface access, extracellular CAZymes and peptidases show functional redundancy, and intracellular catabolic pathways create discrete metabolic
Kangsan Kim +5 more
wiley +1 more source
Mode‐Resolved Phonon Dynamics Under Chemical Pressure in SnTe Thermoelectrics
Advanced Science, EarlyView.Chemical pressure reshapes low‐energy optical phonons in SnTe, altering their dispersion and scattering with heat‐carrying acoustic modes. Positive and negative pressure states modify phonon frequencies and lifetimes in distinct ways, revealing how mode‐selective lattice perturbations regulate acoustic–optical interactions and suppress lattice thermal ...
Zhihao Li +7 more
wiley +1 more source
Advanced Science, EarlyView.A palladium membrane reactor delivers active hydrogen to homogeneous nickel terpyridine catalysts, which then selectively hydrogenate dinitrogen to ammonia. ABSTRACT Ammonia production is a cornerstone of modern industry and society, yet the conventional Haber–Bosch process accounts for nearly 2% of the global CO2 emissions. A promising and potentially
Morgan McKee +11 more
wiley +1 more source
Advanced Science, EarlyView.Synergistically integrating substituent variation and positional isomerism in molecular engineering affords 13 rare tricolored mechanofluorochromic luminogens, and 3 exceedingly scarce force‐triggered bidirectional high‐contrast three‐color fluorescence switches are screened out via a three‐step protocol.
Yijie Zou +7 more
wiley +1 more source
Advanced Electronic Materials, EarlyView.Two series of self‐doped conjugated polyelectrolytes are synthesized from a non‐self‐dopable building block 3MEEET and a self‐dopable building‐block 3HOT−[TMA+] or 3HOT−[SO3H] enabling precise control over the degree of self‐doping, which in turn directly governs the threshold voltage (VT) in OECTs over a wide range of 700 mV.
Julian Hungenberg +7 more
wiley +1 more source