Results 171 to 180 of about 231,798 (197)
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Sulfides in organic synthesis. Application of sulfides
Russian Chemical Reviews, 1994The results of studies on the use of sulfides as synthons in organic synthesis are treated systematically and surveyed. The practical applications of sulfides are examined. The bibliography includes 187 references.
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Reductive Sulfidation. Conversion of Aldehydes into Sulfides
Synthetic Communications, 1976Abstract Carbonyl compounds have been converted into 1,3-oxathiolanes or 1,3-oxathianes and then reduced with “mixed hydride” to β-hydroxyethyl (or on further reduction ethyl) or γ-hydroxypropyl sulfides, respectively.1 However, this overall conversion of a carbonyl compound to a sulfide (a process for which the name reductive sulfidation is suggested ...
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Journal of Experimental Marine Biology and Ecology, 1979
Abstract Life in the sulfide system requires the ability to withstand the toxic effects of long-term sulfide stress. The adaptations of sulfide-system interstitial metazoans to sulfide stress have been investigated using 35 S-sulfide. One possible adaptation, the total exclusion of sulfide at the body wall, could not be demonstrated.
Miles A. Crenshaw+2 more
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Abstract Life in the sulfide system requires the ability to withstand the toxic effects of long-term sulfide stress. The adaptations of sulfide-system interstitial metazoans to sulfide stress have been investigated using 35 S-sulfide. One possible adaptation, the total exclusion of sulfide at the body wall, could not be demonstrated.
Miles A. Crenshaw+2 more
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Photooxidation of methyl sulfide, ethyl sulfide, and methanethiol
Environmental Science & Technology, 1984Products of sunlight-irradiated mixtures of oxides of nitrogen and alkyl sulfides (RSR, R = CH/sub 3/, C/sub 2/H/sub 5/) and methanethiol (CH/sub 3/SH) in air include formaldehyde (R = CH/sub 3/), acetaldehyde and PAN (R = C/sub 2/H/sub 5/), sulfur dioxide, and alkyl nitrates (RONO/sub 2/) as well as particulate alkanesulfonic acids (RSO/sub 2/OH) and ...
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On the volumetric determination of hydrogen sulfide and soluble sulfides
Analytica Chimica Acta, 1953Abstract I. Common sources of eiior in the lodumetric methods fur the determination ol hydiogen sultide and soluble sulfides are discussed. An improved method for the lodometric dctermination is described and its precision and accuracy are discussed. II. The volumetric determination of sulfides by means of alkaline hypochlorite solutions is discussed.
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Chemischer Informationsdienst, 1976
AbstractMessungen der 119Sn‐Mößbauer‐Spektren an einer Reihe von ternären Sulfiden (wie Na4SnS4, Na6Sn2S7, Ba2SnS4, Ba3Sn2S7, Na2SnS3 (Tieftemperaturform) und PbSnS3) bekannter Kristallstruktur zeigen, daß die chemische Isomerenverschiebung auf die Koordinationszahl am Sn‐Zentralatom anspricht und beim Übergang von tetraedrischer über ...
Norman N. Greenwood+2 more
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AbstractMessungen der 119Sn‐Mößbauer‐Spektren an einer Reihe von ternären Sulfiden (wie Na4SnS4, Na6Sn2S7, Ba2SnS4, Ba3Sn2S7, Na2SnS3 (Tieftemperaturform) und PbSnS3) bekannter Kristallstruktur zeigen, daß die chemische Isomerenverschiebung auf die Koordinationszahl am Sn‐Zentralatom anspricht und beim Übergang von tetraedrischer über ...
Norman N. Greenwood+2 more
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Sulfidation Kinetics of Silver Nanoparticles Reacted with Metal Sulfides
Environmental Science & Technology, 2014Recent studies have documented that the sulfidation of silver nanoparticles (Ag-NP), possibly released to the environment from consumer products, occurs in anoxic zones of urban wastewater systems and that sulfidized Ag-NP exhibit dramatically reduced toxic effects.
Eberhard Morgenroth+5 more
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The preparation of metal sulfides and organo-metal sulfides from metal alkyls and hydrogen sulfide
Inorganica Chimica Acta, 1989AbstractThe room temp. reaction of AlR3 (R: Me, Et, iBu) with H2S in toluene gives air‐sensitive solids which are postulated to be mixtures of Al2S3 and polymeric (RAlS)x. A species of the empirical formula MeGaS is produced from GaMe3 and H2S. The reactions of M(CH2‐SiMe3)n (M: Cd, Hg, n = 2; M: Ti, n = 4) and MgEt2 with H2S are also described.
Curtis E. Johnson, Christopher G. Bauch
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Colloid & Polymer Science, 1991
Organosols of NiS, PdS, and MnS in N,N-dimethylformamide were prepared by reaction of the metal acetate with H2S. Organosols of mixed-metal sulfides (ZnxCd1−xS, HgxCd1−xS, HgxCu1−xS, CdxMn1−xS, HgxMn1−xS, HgxCd1−xS, and MnxZn1−xS) were similarly obtained by reaction of mixtures of the metal salts with H2S.
Kenji Kubota+5 more
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Organosols of NiS, PdS, and MnS in N,N-dimethylformamide were prepared by reaction of the metal acetate with H2S. Organosols of mixed-metal sulfides (ZnxCd1−xS, HgxCd1−xS, HgxCu1−xS, CdxMn1−xS, HgxMn1−xS, HgxCd1−xS, and MnxZn1−xS) were similarly obtained by reaction of mixtures of the metal salts with H2S.
Kenji Kubota+5 more
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Sulfide-quinone and sulfide-cytochrome reduction in Rhodobacter capsulatus
Photosynthesis Research, 1994The reduction by sulfide of exogenous ubiquinone is compared to the reduction of cytochromes in chromatophores of Rhodobacter capsulatus. From titrations with sulfide values for Vmax of 300 and 10 μmoles reduced/mg bacteriochlorophyll a·h, and for Km of 5 and 3 μM were estimated, for decyl-ubiquinone-and cytochrome c-reduction, respectively.
Inge Herrman+5 more
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