Results 101 to 110 of about 32,277 (248)

Decoding NASICON and Its Metal Interface for Solid‐State Batteries

Advanced Materials, EarlyView.
This review paper focuses on lithium‐ and sodium‐based NASICON solid electrolytes and their interfaces with metal anodes using a top‐down framework. It begins with NASICON fundamentals, elucidates anode‐induced failure mechanisms, surveys advanced characterization strategies to understand them, summarizes mitigation approaches, and concludes with a ...
Jiaqi Xu, Taiguang Li, Ying Wang, Ruosi Qiao, Quinn Qiao, Yu Chen, Zhou Yu, Chunyi Zhi, Changmin Shi   +8 more
wiley   +1 more source

Low‐Dimensional MOF Nanoarchitectonics: Progress in MOF‐2D Material Hybrid Architectures for Energy Conversion and Storage

Advanced Materials, EarlyView.
This review highlights the integration of metal‐organic frameworks (MOFs) and two‐dimensional (2D) materials through dimensional interface engineering. By addressing intrinsic limitations like poor conductivity and agglomeration, these hybrid architectures optimize interfacial charge and mass transport.
Prashant Dubey, Norman C.‐R. Chen, Xiangyang Liu, Yongqi Yin, Keisuke Shirasaki, Kevin C.‐W. Wu, Yingji Zhao, Yusuke Yamauchi   +7 more
wiley   +1 more source

Superionic Amorphous Li2ZrCl6 and Li2HfCl6

Advanced Materials, EarlyView.
Amorphous Li2HfCl6 and L2ZrCl6 are shown to be promising solid‐state electrolytes with predicted ionic conductivities >20 mS·cm−1. Molecular dynamics simulations with machine‐learning force fields reveal that anion vibrations and flexible MCl6 octahedra soften the Li coordination cage and enhance mobility. Correlation between Li‐ion diffusivity and the
Shukai Yao, De‐en Jiang
wiley   +1 more source

Ga‐on‐In Substitution with Zn Vacancies in Zn3In2S6 Induces Electron–Hole Asymmetry and In─O Bond Weakening for Coupled Two‐Electron Oxygen Reduction and H2O2 Stabilization

Advanced Materials, EarlyView.
Ga‐on‐In substitution coupled with Zn vacancies in Zn3In2S6 creates a dopantdefect synergy that weakens InO bonding and induces electronhole asymmetry. The resulting spatial charge separation directs the two‐electron oxygen reduction pathway, enabling efficient artificial photosynthesis of H2O2 with a production rate of 187.8 µmol g−1 min−1 ...
Xiaowen Ruan, Chunsheng Ding, Dongxu Jiao, Jing Leng, Minghua Xu, Bonan Li, Zhipeng Yu, Xiaoqiang Cui, Jimmy C. Yu, Yongfa Zhu, Sai Kishore Ravi   +10 more
wiley   +1 more source

Self‐Regulating Sodium‐Ion Battery Materials: From Phase Reconstruction to Functional Activation

Advanced Materials, EarlyView.
Self‐regulating sodium‐ion batteries hinge on programmable phase behavior in layered oxides, interphases that renew without growth, and electrolytes that steer solvation and chemistry. This review distills mechanisms into design rules that span composition, site and entropy tuning, and self‐buffering anodes, linking operando evidence to choices and ...
Hong Gao, Dingyi Zhang, Chao Wang, Tianxiao Chen, Xingwang Peng, Yuxiu Xing, Xin Guo, Yufei Zhao, Yong Wang, Guoxiu Wang, Hao Liu   +10 more
wiley   +1 more source

Oxygen Evolution Reaction Catalysts for Acidic‐Media CO2 Electrolyzers

Advanced Materials, EarlyView.
Acidic‐media CO2 electroreduction (CO2R) could decarbonize chemical production, despite relying on rare‐earth elements for anodic oxygen evolution reaction (OER). Transferring the learnings from mature sister technologies (water electrolysis) could accelerate technological development.
Mingcheng Huang, Adnan Ozden
wiley   +1 more source

Low Resistance Interphase Formation at the PEO‐LiTFSI|LGPS Interface in Lithium Solid‐State Batteries

Advanced Materials Interfaces, EarlyView.
Interfacial charge transfer and low‐resistance interphase formation between PEO‐based polymer and Li10GeP2S12 solid electrolytes are investigated using multi‐electrode impedance spectroscopy and advanced analytical techniques such as XPS and ToF‐SIMS.
Ujjawal Sigar, Timo Weintraut, Sebastian L. Benz, Semih Engün, Sascha Kremer, Anja Henss, Felix H. Richter   +6 more
wiley   +1 more source

Using a Zero‐Strain Reference Electrode to Distinguish Anode and Cathode Volume Changes in a Solid‐State Battery

Advanced Materials Interfaces, EarlyView.
Volume changes of a solid‐state battery cell are separated into the individual contributions of anode and cathode. Simultaneously determining the “reaction volumes” of both electrodes requires a reference electrode with a pressure‐independent potential.
Mervyn Soans, Benedikt Huber, Marcel Drüschler, Dominic Bresser, Alberto Varzi, Christoffer Karlsson   +5 more
wiley   +1 more source

Design of High‐Energy Anode for All‐Solid‐State Lithium Batteries–A Model with Borohydride‐Based Electrolytes

Advanced Materials Interfaces, EarlyView.
This study proposes a function‐sharing anode design to enable nonmetallic lithium insertion while maintaining intimate interfacial contact with the solid‐state electrolyte. A combination of lithium‐compatible and conformable borohydrides, highly conformable indium metal, less‐graphitized acetylene black, and a layer of highly graphitized massive ...
Keita Kurigami, Akihiro Ishii, Itaru Oikawa, Hitoshi Takamura   +3 more
wiley   +1 more source

Tailor‐Made Protective LixAlSy Layer for Lithium Anodes to Enhance the Stability of Solid‐State Lithium–Sulfur Batteries

Advanced Materials Interfaces, EarlyView.
An intentionally added, chemically formed LixAlSy coating stabilizes the lithium–electrolyte interface in solid‐state Li–S batteries. The layer suppresses side reactions, preserves smooth charge transfer, and improves ion transport from the start. This approach offers a practical route to more durable solid‐state batteries and a clearer understanding ...
Xinyi Wang, Katja Kretschmer, Sharif Haidar, Georg Garnweitner, Daniel Schröder   +4 more
wiley   +1 more source