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The Solvent Dimethyl Sulfoxide

Angewandte Chemie International Edition in English, 1967
AbstractThe dipolar aprotic solvent dimethyl sulfoxide is liquid over a wide range of temperatures, is a strong electron donor, and has a high polarity. It is therefore an excellent and selective solvent for many organic and even polymeric compounds, and can enter into H‐bonding and dipole‐dipole association. The structure of dimethyl sulfoxide, with a
D, Martin, A, Weise, H J, Niclas
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Reaction of Arynes with Sulfoxides

Organic Letters, 2015
A S-O bond insertion reaction of sulfoxides with arynes is reported. This reaction represents a rare instance of semipolar single bond insertion in aryne chemistry. The study of mechanism indicates that a sulfur ylide triggered by aryne is the key intermediate, which further transfers its methylene group to carbonyl compounds to give epoxides and ...
Hong-Ying, Li   +5 more
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The “Sulfoxide Bond”

Angewandte Chemie International Edition in English, 1972
H, Bock, B, Solouki
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Sulfoxides

1987
C R, Johnson, M P, Westrick
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