Results 51 to 60 of about 7,353 (249)

Variability of sulfur speciation in sediments from Sulejów,Turawa and Siemianówka dam reservoirs (Poland)

open access: yesOpen Geosciences, 2015
A study on sulfur circulation in sediments wascarried out in dam reservoirs (Sulejów, Siemianówka, Turawa)with different hydrological and age characteristicsas well as with a different level of sediment accumulationand organic matter content.Differences ...
Drzewicki Wojciech   +3 more
doaj   +1 more source

The petrology and genesis of the Paleoproterozoic mafic intrusion-hosted Co-Cu-Ni deposit at Hietakero, NW Finnish Lapland [PDF]

open access: yesBulletin of the Geological Society of Finland, 2018
Cobalt is a highly sought-after metal due to its economic importance in many hightech applications. It is mainly obtained from sedimentary-hosted Cu-Co deposits and magmatic Ni-Cu deposits as a by-product. We describe a recently discovered Co-enriched Cu-
Konnunaho, J.P.   +4 more
doaj   +1 more source

Atomically Correlated Phosphorus–Sulfur Sites in Carbon Nitride for Efficient Hydrogen Peroxide Production

open access: yesAdvanced Science, EarlyView.
Atomically correlated phosphorus–sulphur sites are introduced into graphitic carbon nitride to regulate charge distribution, suppress localized trapping, and enhance oxygen activation. The resulting metal‐free photocatalyst selectively promotes the two‐electron oxygen reduction pathway, enabling efficient hydrogen peroxide production in pure water ...
Adnan Ahmad   +12 more
wiley   +1 more source

Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective

open access: yesAngewandte Chemie, EarlyView.
Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie   +11 more
wiley   +2 more sources

Bond‐Competition‐Driven Enhancement of Surface Basicity and Interfacial Interaction to Boost Photocatalytic Syngas Production

open access: yesAdvanced Science, EarlyView.
A synergetic surface bond competition−hybridization approach was developed to synthesize high‐performance CO2 adsorbents and syngas production photocatalysts via the sulfurization‐driven control of surface basicity and interfacial coupling. The ZnIn2S4−sulfur‐doped MgO/MgAl2O4 nanocomposites showed outstanding photocatalytic efficiency for production ...
Dong Wook Lee   +9 more
wiley   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

Fractionation of sulfur isotopes in the preparation of sulfur dioxide. An improved technique for the precision analysis of stable sulfur isotopes

open access: yesGEOCHEMICAL JOURNAL, 1966
It is definitely shown that the main cause of error encountered in the precision isotope analysis of sulfur is in the isotope exchange reaction between SO2 and SO3 during the combustion process of SO2 preparation. The isotope fractionation factor between the two oxides is estimated to be 1.0035 at 1200°C.
Sakai, Hitoshi, Yamamoto, Masahiro
openaire   +2 more sources

Cobalt‐Catalyzed Asymmetric Construction of Boron Stereocenters With C–N Axial Chirality

open access: yesAdvanced Science, EarlyView.
A cobalt/Salox‐catalyzed one‐pot annulation enables enantioselective formation of B‐stereogenic centers and C─N axial chirality via C─H/N─H annulation, affording diverse fluorescent products with high stereocontrol and optoelectronic potential. ABSTRACT The efficient construction of boron stereogenic centers alongside axial chirality remains a ...
Subramani Kumaran   +5 more
wiley   +1 more source

Adaptive Hydrogenation of Alkynes Using CO as a Molecular Trigger to Selectively Produce Alkanes or Z‐Alkenes

open access: yesAngewandte Chemie, EarlyView.
One catalyst for two products: CO acts as a molecular trigger for adaptive alkyne hydrogenation using supported Pd nanoparticles. The catalyst reversibly switches between the formation of alkanes under H2 and Z‐alkenes under H2/CO for 37 structurally diverse alkynes.
Manisha Durai   +7 more
wiley   +2 more sources

Sulfur degassing at Erta Ale (Ethiopia) and Masaya (Nicaragua) volcanoes: Implications for degassing processes and oxygen fugacities of basaltic systems

open access: yesGeochemistry, Geophysics, Geosystems, 2013
We investigate the relationship between sulfur and oxygen fugacity at Erta Ale and Masaya volcanoes. Oxygen fugacity was assessed utilizing Fe3+/∑Fe and major element compositions measured in olivine‐hosted melt inclusions and matrix glasses.
J. M. deMoor   +13 more
doaj   +1 more source

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