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Supercritical Fluids for Organic Synthesis
ChemInform, 2005AbstractFor Abstract see ChemInform Abstract in Full Text.
Ryoji Noyori, Takao Ikariya
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Green organic synthesis in supercritical water [PDF]
Water under supercritical conditions displays unique characteristics because of which it has emerged as an interesting solvent in recent years. It is abundantly available in nature and does not affect the environment, making it a green solvent.
Gaffer Ahmed +3 more
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Supercritical Hydrothermal Reactions for Material Synthesis
Bulletin of the Chemical Society of Japan, 2023Abstract Since the early 1990s, Adschiri and his colleagues have performed research on the use of supercritical water in diverse applications, including heavy oil reforming, waste polymer decomposition and chemical raw materials recovery, cellulose hydrolysis and sugar recovery, lignin decomposition and chemical raw materials recovery ...
Tadafumi Adschiri +14 more
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Supercritical Hydrothermal Synthesis of Nanoparticles
The Proceedings of the Thermal Engineering Conference, 2004Abstract In this chapter, nanoparticle synthesis using supercritical water is introduced. The characteristic phase behavior of supercritical water enables organic ligand modification, and fine tuning of particle size and morphology can be realized by the method. Synthesis of metal nanoparticles is possible in homogeneous reductive atmosphere provided
Tadafumi Adschiri +4 more
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Supercritical Fluid Synthesis of Metal and Semiconductor Nanomaterials
Chemistry – A European Journal, 2003AbstractIn the near future physical and economic constraints are expected to limit the continued miniaturisation of electronic and optical devices using current “top‐down” lithography‐based methods. Consequently, nonlithographic methods for synthesising and organising materials on the nanometre scale are required.
Holmes, Justin D. +2 more
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Ceria–zirconia mixed oxide prepared by continuous hydrothermal synthesis in supercritical water as catalyst support [PDF]
A number of different synthetic methods have been applied to prepare ceria-zirconia and related mixed oxides. Continuous hydrothermal synthesis in supercritical water (supercritical synthesis) is a method to prepare metal oxide nanoparticles rapidly and ...
Son-Ki Ihm, Jeong-Rang Kim
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Synthesis of Phenylferrocene in Supercritical Carbon Dioxide
Advanced Materials Research, 2012The environmentally benign Suzuki cross-coupling reaction was developed by using ScCO2(Supercritical CO2) instead of traditionally organic solvent. In the paper the compound phenylferrocene was synthesized by the Suzuki cross-coupling reaction of iodoferrocene and phenylboronic acids in ScCO2/PEG (polyethylene glycol) with excellent yield ratio in the ...
Fawang Li +3 more
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Fluoropolymer synthesis in supercritical carbon dioxide
The Journal of Supercritical Fluids, 2009Abstract Herein we review the environmentally friendly synthesis of fluorinated polymers in supercritical carbon dioxide (scCO2). Historically, many high-performance fluorinated materials are commercially synthesized in aqueous media using fluorinated surfactants or in non-aqueous conditions using fluorinated solvents.
Libin Du +3 more
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Supercritical Hydrothermal Synthesis of Inorganic Nanomaterials
2019Nanomaterials are always at the leading emerging area of material and nanotechnology. Especially in this age, the ever-increasing population in the world makes energy, chemicals and other resource efficiency particularly important in sustaining concept [1].
Shuzhong Wang +8 more
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Synthesis of cobalt nanoparticles in supercritical methanol
Materials Chemistry and Physics, 2010Abstract Cobalt nanoparticles with a face-centered cubic (fcc) structure were synthesized by the reduction of Co(NO 3 ) 2 in supercritical methanol. The reduction of Co(NO 3 ) 2 to fcc Co was completed within 15 min at 400 °C and 300 bar. The reduction mechanism was investigated by varying the reaction temperature (200–400 °C) and the reaction time
Nae Chul Shin +4 more
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