Results 41 to 50 of about 20,671 (253)
Defect‐Guided Assembly of Aperiodic and Flexible Metal–Organic Frameworks From Pre‐Formed Cages
Angewandte Chemie, EarlyView.A cage‐directed strategy is used to program topologically correlated defects and induce aperiodicity in HKUST‐1‐type MOFs. A missing carboxylate group in the linker drives the formation of Cu‐vacancy domains, while Rh(II) cages spatially confine these defects.
Francisco Sánchez‐Férez +12 more
wiley +2 more sources
Micro-mechanical properties of shale due to water/supercritical carbon dioxide-rock interaction
Petroleum Exploration and Development, 2023 To investigate the impacts of water/supercritical CO2-rock interaction on the micro-mechanical properties of shale, a series of high-temperature and high-pressure immersion experiments were performed on the calcareous laminated shale samples mined from ...
Ning LI +6 more
doaj +1 more source
Advanced Materials, EarlyView.The transition from cryogenic distillation to polymeric sorbents for light hydrocarbon purification is crucial for energy and environmental sustainability. The polymeric sorbents are engineered to separate gas mixtures based on their specific properties.
Kelechi Festus +9 more
wiley +1 more source
ML Workflows for Screening Degradation‐Relevant Properties of Forever Chemicals
Advanced Science, EarlyView.The environmental persistence of per‐ and polyfluoroalkyl substances (PFAS) necessitates efficient remediation strategies. This study presents physics‐informed machine learning workflows that accurately predict critical degradation properties, including bond dissociation energies and polarizability.
Pranoy Ray +3 more
wiley +1 more source
The Gasification of Fructose in Supercritical Water
, 2014 {"references": ["M. J. Antal Jr., S. G. Allen, D. Schulman, X. Xu and R. J. Divilio, \"Biomass gasification in supercritical water,\" Industrial and Engineering Chemistry Research, vol. 39, no. 11, pp. 4040-4053, 2000.", "Y. Matsumura, \"Evaluation of supercritical water gasification and biomethanation for wet biomass utilization in Japan,\" Energy ...
Shyh-Ming Chern, H. Y. Cheng
openaire +3 more sources
Advanced Science, EarlyView.The phase transition of supercritical CO2 induces the foaming of dense MXene film without compromise inherent structure of MXene nanosheet. The foamed porous MXene film manifests remarkable EMI shielding and infrared thermal camouflage performances. Moreover, the foaming strategy is broadly adaptable and can be extended to other two‐dimensional films ...
Hui Zhao +7 more
wiley +1 more source
ZrO2 Aerogel‐Supported Pd Nanoparticles for Photothermal CO2 Reduction
Advanced Science, EarlyView.Nanoparticle‐based aerogels are promising catalysts for photothermal reactions due to optical transparency, high surface area, and low thermal conductivity. Here, we present deposition of Pd nanoparticles on ZrO2 aerogel granules by a wet‐impregnation approach.
David Kiwic +3 more
wiley +1 more source
Polymers and 'strange' liquids
eXPRESS Polymer Letters, 2008 Personal view on ionic liquids and supercritical liquids, especially supercritical water in relation to polymer science.
doaj +1 more source
Accelerated estimation of corrosion rate in supercritical and ultra-supercritical water
npj Materials Degradation, 2017 Corrosion rate: Fast measurement for metals in supercritical water Measurement of corrosion rates in ‘difficult’ environments is an ever-present challenge to corrosion engineers. An accelerated methodology to enable the corrosion rate of steel and nickel
David Rodriguez, Dev Chidambaram
doaj +1 more source
Autonomous High‐Throughput Characterization of Liquid‐Liquid Phase Behavior
Advanced Science, EarlyView.This study introduces an automated dual modality platform, combining asymmetric capacitance deviation and multiangle turbidimetry, for high‐throughput characterization of liquid‐liquid phase behavior across chemically diverse fluid systems. The platform enables miscibility classification, resolution of phase separation kinetics and emulsion stability ...
Tarek Eid +3 more
wiley +1 more source