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This review explains how biomaterials and nanoparticles can be used to induce or modulate tertiary lymphoid structures (TLSs), which are ectopic immune hubs that form in nonlymphoid tissues during chronic disease and cancer. By comparing different methods, the article highlights design principles for modeling TLSs or recapitulating specific TLS ...
Shaza Karaman, Mei ElGindi, Jeremy Teo
wiley +1 more source
Building Molecules by a Self‐Replicator That Catalyzes Acyl Hydrazone Formation
A self‐replicator efficiently catalyzes the formation of acyl hydrazone bonds between a set of different substrates. In addition to previously reported (bond‐breaking) catalytic activity, this renders the self‐replicator highly promiscuous, which is a good starting point for Darwinian experiments en route to de‐novo life.
Kayleigh S. van Esterik +2 more
wiley +1 more source
A Noncovalent Click‐to‐Release Strategy to Control Bond Cleavage and Prodrug Activation
Extending the click‐to‐release concept beyond covalent ligation, we introduce a noncovalent click‐to‐release strategy based on cucurbituril‐adamantane (CB‐Ad) association. A supramolecular preassembly encapsulating a self‐immolative guest (SIG) is rationally designed to prevent premature release, while adding a high‐affinity Ad guest initiates the CB ...
Xuancheng Fu +9 more
wiley +1 more source
Single step site-selective reaction to construct a Ag<sub>2</sub>Au<sub>2</sub> ← Ag<sub>4</sub> supramolecular assembly from hybrid N-heterocyclic carbene (NHC): synthesis, structures and optoelectronic properties. [PDF]
Das P +8 more
europepmc +1 more source
Supramolecular assembly of phenanthrene-DNA conjugates into light-harvesting nanospheres.
Thiede J +5 more
europepmc +1 more source
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Multicharged cyclodextrin supramolecular assemblies
Chemical Society Reviews, 2022This review provides an overview of multicharged cyclodextrin supramolecular assemblies, including their assembly mechanisms and broad applications in chemistry, materials science, medicine, biological science, catalysis, and other fields.
Zhixue Liu, Yu Liu
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Chemical Society Reviews, 2011
The powerful self-assembly features of DNA make it a unique template to finely organize and control matter on the nanometre scale. While DNA alone offers a high degree of fidelity in its self-assembly, a new area of research termed 'supramolecular DNA assembly' has recently emerged.
Christopher K, McLaughlin +2 more
openaire +2 more sources
The powerful self-assembly features of DNA make it a unique template to finely organize and control matter on the nanometre scale. While DNA alone offers a high degree of fidelity in its self-assembly, a new area of research termed 'supramolecular DNA assembly' has recently emerged.
Christopher K, McLaughlin +2 more
openaire +2 more sources
Supramolecular assemblies of carotenoids
Chirality, 2001AbstractCarotenoid self‐assemblies were formed by aqueous dilution of ethanolic solutions. The four 3′,6′‐epimers of capsanthol ((all‐E,3R,5′R)‐3,3′,6′‐trihydroxy‐β,κ‐carotene) give rise to right‐ and left‐handed card‐pack and head‐to‐tail types of self‐assemblies detected by exciton couplets appearing in the CD spectra.
F, Zsila +3 more
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Supramolecular Systems: Self‐Assembly
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
R.M. Yeh, A.V. Davis, K.N. Raymond
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