Self‐Assembled Polymeric Supramolecular Frameworks
Within the framework: Ionic complexation of diblock copolypeptide poly(γ-benzyl-L-glutamate)-block-poly(L-lysine) (PBLG-b-PLL) with 2′-deoxyguanosine 5′-monophosphate (dGMP, gray) generates a polymeric supramolecular framework solid with self-assembled cages based on two orthogonal shape-persistent motifs: PBLG α helices (blue) and PLL β sheets (red ...
Haataja, Johannes S. +7 more
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Quantum-Chemical Insights into the Self-Assembly of Carbon-Based Supramolecular Complexes
Understanding how molecular systems self-assemble to form well-organized superstructures governed by noncovalent interactions is essential in the field of supramolecular chemistry.
Joaquín Calbo +3 more
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Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex [PDF]
Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine the effect of weak metal-metal and π-π ...
Adamovich +36 more
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Supramolecular Chemistry and Self‐assembly. [PDF]
Supramolecular systems—their successes, problems, and potential—are discussed with allusion to specific examples.
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Exploiting Peptide Self-Assembly for the Development of Minimalistic Viral Mimetics
Viruses are natural supramolecular nanostructures that form spontaneously by molecular self-assembly of complex biomolecules. Peptide self-assembly is a versatile tool that allows mimicking viruses by creating their simplified versions through the design
Patrizia Janković +4 more
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Ortho-Fluorination of azophenols increases the mesophase stability of photoresponsive hydrogen-bonded liquid crystals [PDF]
Photoresponsive liquid crystals (LCs) whose alignment can be controlled with UV-Visible light are appealing for a range of photonic applications. From the perspective of exploring the interplay between the light response and the self-assembly of the ...
Ahmed Z. +5 more
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Supramolecular self-assembled fullerene nanostructures [PDF]
Four ionic fullerene derivatives, which are relatively soluble in polar solvents, are shown to organize into morphologically different nanoscale structures. Spheres, nanorods, and nanotubules form in water depending on the side chain appendage of the fullerene spheroid.
V. GEORGAKILAS +5 more
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Noncovalent self‐assembly creates an effective route to highly sophisticated supramolecular polymers with tunable properties. However, the outcome of this assembly process is highly dependent on external conditions.
Grzegorz Markiewicz +2 more
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Investigations into the assembly behaviour of a 'rigidified': P-carboxylatocalix[4]arene [PDF]
The p-carboxylatocalix[4]arenes have been shown to be versatile supramolecular building blocks capable of forming a range of bi-layers, capsules and nanoscale tubules in the solid state.
Alfieri +39 more
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Self-assembled supramolecular nanostructure photosensitizers for photocatalytic hydrogen evolution
Supramolecular self-assembly as a breakthrough methodology in the nanoscience and nanotechnology fields has attracted increasing attention. Highly ordered self-assembled supramolecular nanostructures aim to emulate natural light-harvesting and energy ...
Yong Zhong +6 more
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