Results 81 to 90 of about 52,059 (299)

Conjugated Porphyrin Polymer With Superior Charge Transfer for Photodynamic‐Immunomodulatory Prevention of CIED Infection in Diabetes

open access: yesAdvanced Healthcare Materials, EarlyView.
Under NIR irradiation, PTCPP generates ROS to eliminate MRSA biofilms and promote M1 macrophage polarization for phagocytosis. After bacterial clearance, the material is phagocytosed by macrophages, shifting their polarization to M2 phenotype via metabolic reprogramming, which synergistically enhances anti‐infection therapy and wound healing.
Honghao Ma   +13 more
wiley   +1 more source

Supramolecular hybrid bidentate ligands in asymmetric hydrogenation [PDF]

open access: yes, 2012
In this study we introduce a novel class of supramolecular bidentate hybrid ligands and their application in the rhodium-catalysed asymmetric hydrogenation of prochiral olefins.
Rosalba Bellini   +3 more
core   +1 more source

Supramolecular Chirality in Azobenzene-Containing Polymer System: Traditional Postpolymerization Self-Assembly Versus In Situ Supramolecular Self-Assembly Strategy [PDF]

open access: yes, 2020
Recently, the design of novel supramolecular chiral materials has received a great deal of attention due to rapid developments in the fields of supramolecular chemistry and molecular self-assembly.
Yilin Qian   +5 more
core   +1 more source

Progress in synthesis method of micro/ nano-structured graphitic carbon nitride

open access: yesCailiao gongcheng
The micro/nano-structured graphitic carbon nitride has been widely used in photocatalytic splitting water to hydrogen/oxygen, photocatalytic degradation of organic pollutants, photocatalytic organic synthesis, sensors and biomedicine, and has become one ...
CHENG Si   +5 more
doaj   +1 more source

Self‐Assembled Polymeric Supramolecular Frameworks

open access: yesAngewandte Chemie, 2011
Within the framework: Ionic complexation of diblock copolypeptide poly(γ-benzyl-L-glutamate)-block-poly(L-lysine) (PBLG-b-PLL) with 2′-deoxyguanosine 5′-monophosphate (dGMP, gray) generates a polymeric supramolecular framework solid with self-assembled cages based on two orthogonal shape-persistent motifs: PBLG α helices (blue) and PLL β sheets (red ...
Haataja, Johannes S.   +7 more
openaire   +5 more sources

Stepwise On‐Surface Synthesis and Transformations of Two‐Dimensional Covalent Organic Frameworks by Controlled Thermal Stimuli

open access: yesAdvanced Materials, EarlyView.
The seminal transformation of a 2D‐COF (SURFCOF‐IMDEA1) into a 2D porous COF (SURFCOF‐IMDEA2) on Au(111) by a sequential C‐C coupling and ladderization triggered by thermal annealing steps at increasing temperatures is reported. Abstract The development of covalent organic frameworks (COFs) is currently a primary objective in materials science, taking ...
Ana Barragán   +11 more
wiley   +1 more source

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, EarlyView.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

Assembly of a Supramolecular Capsule on a Molecular Printboard

open access: yesJournal of the American Chemical Society, 2004
A molecular capsule based on ionic interactions between two oppositely charged calix[4]arenes, 1 and 2, was assembled both in solution and on a surface. In solution, the formation of the equimolar assembly 1.2 was studied by (1)H NMR, ESI-MS, and isothermal titration calorimetry, giving an association constant (K(a)) of 7.5 x 10(5) M(-1).
CORBELLINI F.   +8 more
openaire   +3 more sources

Eutectozymes as Soft Hybrid Materials for Advanced Biocatalysis

open access: yesAdvanced Materials, EarlyView.
Eutectozymes are sustainable hybrid materials that embed a GOx–HRP cascade within hydrophobic eutectogels featuring a dual supramolecular–covalent network. This architecture preserves native enzyme structure and stability, enables efficient heterogeneous biocatalysis in aqueous media, and positions eutectogels as robust platforms for next‐generation ...
Manuel Eduardo Martinez Cartagena   +10 more
wiley   +1 more source

Pyrene-DNA Conjugates: Influence of sticky Ends on the Supramolecular Self-Assembly [PDF]

open access: yes, 2022
The supramolecular assembly of DNA conjugates has caught attention in supramolecular chemistry. DNA bears some unique features enabling the design of complex nanostructures. The DNA framework offers a defined spatial arrangement of modifications.
Langenegger, Simon M.   +2 more
core  

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