Results 81 to 90 of about 3,671 (216)
Through simultaneous molecular and supramolecular engineering, an atomically precise nanocluster Cu16 with ambient ultrastability and ultrabright luminescence is constructed. Cu16 employs a dual structural/luminescent channel mechanism to achieve orthogonal responsiveness to five external stimuli, demonstrating multidimensional signalling capability ...
Leon Li‐Min Zhang +7 more
wiley +1 more source
The compound was prepared by dissolving 2-(phenylamino)pyridine (0.52 g ; 3.0 mmol) and di(methanesulfonyl)amine (0.51 g; 3.0 mmol) in 5 mL methanol. Slow partial evaporation of the solvent at low tempertaure (-30 oC) gave a yield of 0.66 g (64%) and ...
Karna Wijaya +4 more
doaj +1 more source
Application of Halogen Bonding to Organocatalysis: A Theoretical Perspective
The strong, specific, and directional halogen bond (XB) is an ideal supramolecular synthon in crystal engineering, as well as rational catalyst and drug design.
Hui Yang, Ming Wah Wong
doaj +1 more source
Crystal structure of the (E)-O-methyl-N-phenyl-thiocarbamate – 4,4′-bipyridine (1/1), C18H17N3OS [PDF]
C18H17N3OS, monoclinic, C2/c (no. 15), a=13.4754(3) Å, b=13.8997(3) Å, c=18.0300(4) Å, β=107.202(3)°, V =3226.03(13) Å3, Z =8, Rgt(F)=0.0341, wRref(F2)=0.0878, T =100(2 ...
Tiekink, Edward R. T. * +1 more
core +1 more source
Organic and Metallacages for Chemical Sensing: Progress in Water‐Compatible Systems
Supramolecular cages function as three‐dimensional receptors for selective molecular recognition and sensing, and this review outlines design principles for water‐stable architectures, key analyte‐ and medium‐dependent challenges, recent water‐compatible examples (including polymer‐integrated systems), and future opportunities for cage‐based ...
Rabia Zahid +4 more
wiley +1 more source
Mechanochemical Synthesis of Pharmaceutical Cocrystal Suspensions via Hot Melt Extrusion: Feasibility Studies and Physicochemical Characterisation [PDF]
Engineered cocrystals offer an alternative solid drug form with tailored physicochemical properties. Interestingly, although cocrystals provide many new possibilities, they also present new challenges, particularly in regard to their design and large ...
Andrews, Gavin P. +5 more
core +1 more source
Hydrogen bonding in 2,6-bis(4-fluorophenyl)-3,5-dimethylpiperidin-4-one methanol solvate [PDF]
The crystal structure analysis of a 2,6-diaryl 4-piperidone derivative, isolated as a mono-methanol solvate, reveals that both the piperidone and the methanol molecule lie on a crystallographic mirror plane.
Jotani, Mukesh M. +7 more
core +1 more source
1-Benzoyl-3-methyl-3-pentylthiourea
Two independent molecules comprise the asymmetric unit of the title compound, C14H20N2OS. These differ in the relative orientations of the pentyl chains [C—C—C—C torsion angles = −176.7 (3) and 176.4&#
N. Gunasekaran +4 more
doaj +1 more source
Prediction of supramolecular synthons and crystal packings of supramolecular HMX/solvent assemblies
We report the most stable packings of five HMX/solvent supramolecular assemblies.
Zhichao Liu +3 more
openaire +2 more sources
Triggered formation of thixotropic hydrogels by balancing competitive supramolecular synthons [PDF]
Two component hydrogels have been obtained by formation of 1:1 complexes of bis(pyridyl urea)s with a range of dicarboxylic acids. The gels are thixotropic and undergo an assembly process in which short segments can reversibly assemble into an interconnected fibrous network.
Liu, K., Steed, J. W.
openaire +3 more sources

