Results 101 to 110 of about 106,351 (226)
It is demonstrated that the self‐assembly process of the 3‐pyridyl‐based TBNap structure is highly solvent deepened. X‐ray diffraction analysis confirms that the TBNap structure possesses solvent‐depended packing arrangements in the crystalized form.
Sankarasekaran Shanmugaraju +6 more
wiley +1 more source
New Schiff base complexes [Cu2(HL1)(L1)(N3)3]∙2H2O (1) and [Cu2L2(N3)2]∙H2O (2) were synthesized. The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis.
O. V. Nesterova +2 more
semanticscholar +1 more source
Triggered formation of thixotropic hydrogels by balancing competitive supramolecular synthons [PDF]
Two component hydrogels have been obtained by formation of 1:1 complexes of bis(pyridyl urea)s with a range of dicarboxylic acids. The gels are thixotropic and undergo an assembly process in which short segments can reversibly assemble into an interconnected fibrous network.
Liu, K., Steed, J. W.
openaire +3 more sources
(2E)-N′-Benzoyl-3-(4-nitrophenyl)prop-2-enohydrazide
In the title compound, C16H13N3O4, the dihedral angle between the terminal benzene rings is 14.02 (7)°. The carbonyl groups are anti with respect to each other, which facilitates their participation in the formation of supramolecular ...
Samir A. Carvalho +5 more
doaj +1 more source
Expanding Chemistry of Expanded Helicenes
This review presents recent advances in the chemistry of expanded helicenes, defined as helicenes containing linearly fused benzene rings, as novel aromatic compounds. This review begins with a summary of their structural classification, followed by the synthesis, structures, properties, and chiroptical performance of expanded helicenes of various ...
Shinji Toyota
wiley +1 more source
In the title compound, C20H19FN6S, the pyrazole ring has an envelope conformation, with the methine C atom being the flap atom. The dihedral angle between the least-squares plane through the pyrazole and triazole rings is 7.59 (9)° ...
Bakr F. Abdel-Wahab +3 more
doaj +1 more source
Tautomerism‐Coupled Self‐Assembly and Transformations of Iminopyrrole Metallacages
Four metallacages with varying size, symmetry, and nuclearity were formed via the self‐assembly of 2,5‐diformylpyrrole, tren, and zinc(II) acetate. Tautomerization of the key diiminopyrrole motif to iminoaminoazafulvene altered the assemblies’ properties.
Jakub Sukiennik +4 more
wiley +1 more source
Investigations into the assembly behaviour of a 'rigidified': P-carboxylatocalix[4]arene [PDF]
The p-carboxylatocalix[4]arenes have been shown to be versatile supramolecular building blocks capable of forming a range of bi-layers, capsules and nanoscale tubules in the solid state.
Alfieri +39 more
core +2 more sources
Crystal structure of 2-(4-chlorobenzamido)benzoic acid
In the title molecule, C14H10ClNO3, the amide C=O bond is anti to the o-carboxy substituent in the adjacent benzene ring, a conformation that facilitates the formation of an intramolecular amide-N—H...O(carbonyl) hydrogen bond that closes an S(6) loop ...
Rodolfo Moreno-Fuquen +2 more
doaj +1 more source
Hydrogen-bonding synthons in lamotrigine salts: 3,5-diamino-6-(2,3-dichlorophenyl)-1,2,4-triazin-2-ium 2-[(2-carboxyphenyl)disulfanyl]benzoate in its monohydrate and anhydrous forms [PDF]
Lamotrigine is a drug used in the treatment of epilepsy and related convulsive diseases. The drug in its free form is rather inadequate for pharmacological use due to poor absorption by the patient, which limits its bioavailability.
Baggio, Ricardo Fortunato +2 more
core +1 more source

