It is demonstrated that the photoinduced cycloreversion of a methoxynaphthylquadricyclane in the presence of suitable photocatalysts gives quantitatively the corresponding norbornadiene. As this photochromic norbornadiene‐quadricyclane cycle has favorable properties for light energy conversion, this method provides a useful tool for the targeted ...
Julian Felix Maria Hebborn +4 more
wiley +1 more source
Parenchymal loop technique using a novel 0.018-inch guidewire in endoscopic ultrasound-guided pancreatic duct drainage. [PDF]
Oishi R +6 more
europepmc +1 more source
Nitrogen–boron–nitrogen (NBN)‐substituted molecular propellers are presented as structural framework for aggregation induced emission (AIE) applications. Steric hindrance is revealed to steer maximum‐AIE behavior, leading to refined control over assembly‐induced luminescence.
Nico Groß +4 more
wiley +1 more source
Analyzing the Solvent Effects in Palladium/<i>N</i>-Heterocyclic Carbene (Pd/NHC)-Catalyzed Suzuki-Miyaura Coupling of Aryl Chlorides: A Computational Study of the Oxidative Addition Step with Experimental Validation. [PDF]
Collier M +6 more
europepmc +1 more source
Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome +6 more
wiley +1 more source
A Versatile System of Solvent, Catalyst, and Ligand for Challenging Biphenyl Synthesis Through Suzuki-Miyaura Reactions. [PDF]
Al-Joumhawy MK, Chang JC, Gabel D.
europepmc +1 more source
Synthesis of Dithienylcycloalkene Molecular Switches Enabled by a Bench‐Stable Ti‐Complex
Herein we report a set of cycloalkene‐bridged DTEs with ring sizes ranging from 4‐ to 7‐membered rings. The synthesis of these analogs was performed via a key McMurry coupling step, which was enabled by a practical, bench‐stable Ti(IV)‐complex. Remarkably, it is shown that the strained cyclobutene bridge outperforms other rings, even the most commonly ...
Marcell M. Bogner +4 more
wiley +1 more source
AASLD practice guidance on drug, herbal, and dietary supplement–induced liver injury
Hepatology, EarlyView.
Robert J. Fontana +6 more
wiley +1 more source
Postsynthetic modification of amine functionalized MIL-101(Cr) loaded with Pd nanoparticles for sustainable Suzuki coupling reactions. [PDF]
Abroudi M +5 more
europepmc +1 more source
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley +1 more source

