Fluorescent Diarylethenes With Polar Groups: Synthesis, Spectra, and Optical Microscopy Applications
Chemistry – A European Journal, EarlyView.Blinking green and flashing red: photo‐switchable and photo‐activatable probes emitting green and red light were prepared and applied as bioconjugates in super‐resolution optical microscopy. ABSTRACT The use of photoactivatable fluorescent diarylethenes (fDAEs) in biology‐related light microscopy has been restricted by the lack of probes having freely ...
Kakishi Uno +6 more
wiley +1 more source
Impact of Sodium-Glucose Co-transporter 2 Inhibitors After Discharge in Patients With Heart Failure With Reduced Activities of Daily Living: A Single-Center Retrospective Cohort Study. [PDF]
CureusSuzuki M +4 more
europepmc +1 more source
Twisted 1‐ and 2‐Azaperopyrenes: Synthesis, Structure, and Properties
Chemistry – A European Journal, EarlyView.ABSTRACT A synthesis of hitherto unknown 1‐ and 2‐azaperopyrenes, twisted nitrogen‐doped peropyrenes, is reported. The synthesis is based on a Brønsted acid‐mediated benzannulation of alkynes. Key alkyne intermediates are synthesized via two complementary routes, including a Pd/C‐catalyzed, copper‐ and amine‐free Sonogashira‐type coupling of (hetero ...
Ricardo Molenda +4 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.ABSTRACT We explored aryl thianthrenation as a tool for directly incorporating multiple isotopes into molecular scaffolds starting from full isotopically labeled benzene. Stable isotope‐labeled (SIL) molecules are indispensable tools for investigating chemical and biological mechanisms and quantifying metabolites.
Alexandre Labiche +7 more
wiley +1 more source
Real-world effectiveness and safety of lebrikizumab maintenance dosing every 4 weeks starting at week 4 after 2 loading doses in Japanese patients with atopic dermatitis. [PDF]
JAAD IntOkada Y +12 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.A donor–π–acceptor–π–donor (D–π–A–π–D) fluorophore bearing a U‐shaped dipyridophenazine core forms bifurcated hydrogen bonds with neutral donors such as sulfonamides or water. This interaction modulates both ground and excited states, enabling red‐shifted emission and enhanced photoluminescence in solution and solid state.
Kimiya Takei +7 more
wiley +1 more source
Five-year survival of patients with non-small cell lung cancer treated with alkalization therapy. [PDF]
Transl OncolKachi S +5 more
europepmc +1 more source
Pd‐Catalyzed C─C Bond Borylation of Biphenylenes Leading to Tri‐Ortho‐Substituted Biaryls
Chemistry – A European Journal, EarlyView.Palladium‐catalyzed ring‐opening C─C borylation of 1‐substituted biphenylenes yields a range of o,o,o′‐trisubstituted biaryls with two ortho‐boryl groups via selective cleavage of the least hindered C─C bond. The resulting diborylated products are readily amenable to sequential, site‐selective postfunctionalization.
Robyn V. Presland +5 more
wiley +1 more source
Ultrasonic-assisted, additive-free Pd-catalyzed Suzuki-Miyaura cross-coupling enabled synthesis of novel arylated benzofuran-triazole hybrids. [PDF]
Front ChemSaif MJ +9 more
europepmc +1 more source
Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis
Chemistry – A European Journal, EarlyView.Mechanochemistry offers a sustainable, solvent‐free alternative to traditional synthesis, often enhanced by additives in a process known as additive‐assisted grinding. This review discusses how various additives, including liquids, ionic solids, and advanced materials like ionic liquids and piezoelectric compounds, improve reaction efficiency ...
Johanna Breinsperger +3 more
wiley +1 more source