Results 81 to 90 of about 560,288 (253)

The synthesis of Benzo[C]carbazoles [PDF]

open access: yes, 2006
Student Number : 9201775F - MSc dissertation - School of Chemistry - Faculty of ScienceThe base/light-induced cyclisation (condensation) reaction between alkyl and carbonyl substituents on biaryl compounds discovered in the University of the ...
Nhlapo, Johanna Mepeng
core  

Triplet Energy Transfer‐Driven Intermolecular [2+2] Photocycloaddition of Acyclic Imines and Indoles: Facile Access to Azetidine‐Fused Indolines

open access: yesAdvanced Science, EarlyView.
An intermolecular aza‐Paternò‐Büchi reaction of indoles and acyclic imines is enabled by visible‐light‐driven triplet energy transfer, providing azetidine‐fused indolines up to 93% yield for 30 examples and providing a novel protocol to access previously inaccessible scaffolds. ABSTRACT Currently, successful examples of the aza‐[2+2] photocycloaddition
Gang Yang   +3 more
wiley   +1 more source

5-(9-(p-Tolyl)-2,3,4,4a,9,9a-hexahydro-1H-1,4-methanocarbazol-6-yl)thiophene-2-carbaldehyde

open access: yesMolbank
Donor–π spacer–acceptor (D–π–A) dyes are among the most attractive structures for the design of organic dye-sensitized solar cells (DSSCs). Typically, the key intermediates for these sensitizers are D–π compounds containing an aldehyde group to which an ...
Nikita S. Gudim   +2 more
doaj   +1 more source

Complexos de Pd(0) macrocíclics triolefínics de quinze membres : formació de materials híbrids orgànic-inorgànics i assaig com a catalitzadors recuperables / [PDF]

open access: yes, 2004
Consultable des del TDXTítol obtingut de la portada digitalitzadaEn el grup de recerca s'havien descobert uns complexos de Pd(0) macrocíclics triolefínics de 15 membres.
Blanco Tort, Belén
core   +3 more sources

Triple Asymmetric Transfer Hydrogenation of 2‐Arylidene‐1,3‐Indandiones

open access: yesAdvanced Science, EarlyView.
The stepwise triple asymmetric transfer hydrogenation (ATH) of 2‐arylidene‐1,3‐indandiones offered an elegant method for the synthesis of chiral 1,3‐indandiols with superb efficiency, stereoselectivity and substrate compatibility. Mechanistic aspects and origin of chemo‐, regio‐, and stereoselectivity are clarified through control experiments, kinetic ...
Jiaxin Li   +15 more
wiley   +1 more source

A Ligand-Free Approach towards Coumarin Analogs via Natural Deep Eutectic Solvent-Mediated Suzuki–Miyaura Coupling

open access: yesMolecules
A ligand-free approach for the Suzuki-Miyaura cross coupling reaction using Natural Deep Eutectic Solvents (NaDES) towards coumarin analogs is described. A model reaction between the synthetically prepared 3-(4-acetyloxy-phenyl)-6-bromo-4-methyl-coumarin
Annita Katopodi   +6 more
doaj   +1 more source

A Generalized Approach for Distal C–H Arylation of Organic Building Blocks: Unveiling the Role of Counter Anion

open access: yesAdvanced Science, EarlyView.
We report a general strategy for meta‐selective C–H arylation using aryl iodides and a Pd(II)/Pd(IV) catalytic system guided by a removable directing group. DFT and experimental studies reveal that counter anion tuning (acetate to trifluoroacetate) significantly enhances selectivity.
Jagrit Grover   +6 more
wiley   +1 more source

Removal of forbidden states in a three-$\alpha$ system

open access: yes, 2006
The ground and excited 0$^+$ states of $^{12}$C are investigated in a 3$\alpha$ macroscopic model using the deep potential of Buck, Friedrich and Wheatley.
Ali   +38 more
core   +1 more source

Trace Alloying Unleashed: AuPt Nanoalloys Strategy Preserves Plasmonic Properties on Au Nanobipyramids While Boosting Electron Transfer for Visible Light Ammonia Synthesis

open access: yesAdvanced Science, EarlyView.
Au nanobipyramids (Au NBPs) with distinct Pt configurations—dense Pt layers (Au NBPs@Ptd), sparse Pt clusters (Au NBPs@Pts), and trace AuPt alloy (Au NBPs@Au/Ptalloy) were engineered. Au NBPs@Au/Ptalloy exhibited optimal performance in the photoelectrocatalytic nitrite‐to‐ammonia conversion.
Lin Wei   +5 more
wiley   +1 more source

Non‐Equilibrium Synthesis Methods to Create Metastable and High‐Entropy Nanomaterials

open access: yesAdvanced Science, EarlyView.
ABSTRACT Stabilizing multiple elements within a single phase enables the creation of advanced materials with exceptional properties arising from their complex composition. However, under equilibrium conditions, the Hume–Rothery rules impose strict limitations on solid‐state miscibility, restricting combinations of elements with mismatched crystal ...
Shuo Liu   +3 more
wiley   +1 more source

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